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@ARTICLE{Hou:907667,
author = {Hou, Xu and Pollard, Travis P and He, Xin and Du, Leilei
and Ju, Xiaokang and Zhao, Wenguang and Li, Meirong and
Wang, Jun and Paillard, Elie and Lin, Hai and Sun, Jingyu
and Xu, Kang and Borodin, Oleg and Winter, Martin and Li,
Jie},
title = {“{W}ater‐in‐{E}utectogel” {E}lectrolytes for
{Q}uasi‐{S}olid‐{S}tate {A}queous {L}ithium‐{I}on
{B}atteries},
journal = {Advanced energy materials},
volume = {12},
number = {23},
issn = {1614-6832},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2022-02144},
pages = {2200401 -},
year = {2022},
abstract = {The development of high safety lithium-ion batteries (LIBs)
is greatly impeded by the flammability and leakage concerns
of typical organic solvent-based electrolytes. As one of the
alternative classes of electrolytes, hydrogel electrolytes
exhibit high safety, high flexibility, low cost, and are
benign to the environment. However, the narrow
electrochemical stability window (ESW) of typical hydrogel
electrolytes restricts the operating voltage of battery
cells. Here, a new class of “water-in-eutectogel
(WiETG)” electrolyte is reported, fabricated by combining
a hydrogel with a “deep eutectic solvent” (LiTFSI in
acetamide). The obtained WiETG electrolyte exhibits
non-flammability, high ionic conductivity, and a wide ESW.
LiMn2O4||Li4Ti5O12 cells with the WiETG electrolyte exhibit
good cycling stability, high flexibility, and high safety.
This newly developed WiETG electrolyte not only broadens the
ESW of typical hydrogel electrolytes, but also opens a new
perspective on future directions and guidance for the design
of high safety electrolytes for flexible LIBs and beyond.},
cin = {IEK-12},
ddc = {050},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {1221 - Fundamentals and Materials (POF4-122)},
pid = {G:(DE-HGF)POF4-1221},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000791450500001},
doi = {10.1002/aenm.202200401},
url = {https://juser.fz-juelich.de/record/907667},
}