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@ARTICLE{Liang:907707,
      author       = {Liang, Zhifu and Wang, Jianghao and Tang, Pengyi and Tang,
                      Weiqiang and Liu, Lijia and Shakouri, Mohsen and Wang, Xiang
                      and Llorca, Jordi and Zhao, Shuangliang and Heggen, Marc and
                      Dunin-Borkowski, Rafal E. and Cabot, Andreu and Wu, Hao Bin
                      and Arbiol, Jordi},
      title        = {{M}olecular engineering to introduce carbonyl between
                      nickel salophen active sites to enhance electrochemical
                      {CO}2 reduction to methanol},
      journal      = {Applied catalysis / B},
      volume       = {314},
      issn         = {0926-3373},
      address      = {Amsterdam},
      publisher    = {Elsevier},
      reportid     = {FZJ-2022-02170},
      pages        = {121451 -},
      year         = {2022},
      abstract     = {The electrochemical reduction of CO2 to methanol is a
                      potentially cost-effective strategy to reduce the
                      concentration of this greenhouse gas while at the same time
                      producing a value-added chemical. Herein, we detail a highly
                      efficient 2D nickel organic framework containing a large
                      density of highly dispersed salophen NiN2O2 active sites
                      toward electrochemical CO2RR to methanol. By tuning the
                      ligand environment of the salophen NiN2O2, the
                      electrocatalytic activity of the material toward CO2
                      reduction can be significantly improved. We prove that by
                      introducing a carbonyl group at the ligand environment of
                      the Ni active sites, the electrochemical CO2 reduction
                      activity is highly promoted and its product selectivity
                      reaches a Faradaic efficiency of $27\%$ toward the
                      production of methanol at − 0.9 V vs RHE. The
                      salophen-based π-d conjugated metal-organic framework
                      presented here thus provides the best performance toward CO2
                      reduction to methanol among the previously developed
                      nickel-based electrocatalysts.},
      cin          = {ER-C-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ER-C-1-20170209},
      pnm          = {5351 - Platform for Correlative, In Situ and Operando
                      Characterization (POF4-535) / ESTEEM3 - Enabling Science and
                      Technology through European Electron Microscopy (823717)},
      pid          = {G:(DE-HGF)POF4-5351 / G:(EU-Grant)823717},
      typ          = {PUB:(DE-HGF)16},
      doi          = {10.1016/j.apcatb.2022.121451},
      url          = {https://juser.fz-juelich.de/record/907707},
}