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| Hauptseite > Publikationsdatenbank > Defining Aging Marker Molecules of 1,3‐Propane Sultone for Targeted Identification in Spent LiNi 0.6 Co 0.2 Mn 0.2 O 2 ||AG Cells > print |
| Hauptseite > Publikationsdatenbank > Defining Aging Marker Molecules of 1,3‐Propane Sultone for Targeted Identification in Spent LiNi 0.6 Co 0.2 Mn 0.2 O 2 ||AG Cells > print |
| 001 | 907843 | ||
| 005 | 20240712113055.0 | ||
| 024 | 7 | _ | |a 10.1002/ente.202200189 |2 doi |
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| 037 | _ | _ | |a FZJ-2022-02241 |
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| 100 | 1 | _ | |a Peschel, Christoph |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Defining Aging Marker Molecules of 1,3‐Propane Sultone for Targeted Identification in Spent LiNi 0.6 Co 0.2 Mn 0.2 O 2 ||AG Cells |
| 260 | _ | _ | |a Weinheim [u.a.] |c 2022 |b Wiley-VCH |
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| 520 | _ | _ | |a Herein we report on an analytical approach for targeted identification of hazardous 1,3-propane sultone (PS) in spent lithium ion battery material. PS decomposition is investigated with chromatographic techniques coupled to high-resolution accurate mass spectrometry. Speciation of sulfur-containing decomposition products is performed and aging marker molecules are defined. The observed PS decomposition results in characteristic 1-propanesulfonate via electrochemical ring-opening. Based on this, 1-propanesulfonate is defined as an ionic marker molecule for electrochemical PS decomposition. Further, volatile methyl and ethyl esters of 1-propanesulfonate are identified. Their formation is observed mainly caused by elevated temperatures after preceding PS ring-opening during cell formation. Both, ionic and volatile decomposition markers can be applied for targeted identification of hazardous PS-containing lithium ion battery material, despite possible consumption of the initial additive molecule. |
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| 700 | 1 | _ | |a Nowak, Sascha |0 0000-0003-1508-6073 |b 5 |e Corresponding author |
| 773 | _ | _ | |a 10.1002/ente.202200189 |g p. 2200189 - |0 PERI:(DE-600)2700412-0 |n 5 |p 2200189 - |t Energy technology |v 11 |y 2022 |x 2194-4288 |
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