Home > Publications database > Underlying mechanism of shear-banding in soft glasses of charged colloidal rods with orientational domains > print |
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245 | _ | _ | |a Underlying mechanism of shear-banding in soft glasses of charged colloidal rods with orientational domains |
260 | _ | _ | |a Melville, NY [u.a.] |c 2022 |b Inst. |
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520 | _ | _ | |a Soft glasses of colloidal rods (fd-virus particles) with orientational domains were recently shown to exhibit inhomogeneous flow profiles [Dhont et al., Phys. Rev. Fluids 2, 043301 (2017)]: fracture and accompanied plug flow at small shear rates, which transits to gradient shear-banding on increasing the shear rate, while a uniform flow profile develops at sufficiently high shear rates. These flow profiles coexist with Taylor-vorticity bands. The texture of such glasses under flow conditions consists of domains with varying orientations. The observed gradient shear-banding was solely attributed to the strong shear thinning behavior of the material inside the domains (henceforth abbreviated as domain-interior), without considering the texture stress that is due to interactions between the glassy domains. Here, we present new experiments on the shear-banding transition to assess the role played by the texture stress in comparison to the domain-interior stress. For a large concentration, well into the glassy state, it is found that both texture stress and domain-interior stress contribute significantly to the gradient shear-banding transition in the shear-rate region where it occurs. On the other hand, for a small concentration close to the glass-transition concentration, the domains are shown to coalesce within the shear-rate range where gradient shear-banding is observed. As a result, the texture stress diminishes and the domain-interior stress increases upon coalescence, leading to a stress plateau. Thus, a subtle interplay exists between the stresses arising from the structural order on two widely separated length scales from interactions between domains and from the rod-rod interactions within the domain-interior for both concentrations.I. INTRODUCTION |
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700 | 1 | _ | |a Vlassopoulos, D. |0 0000-0003-0866-1930 |b 1 |
700 | 1 | _ | |a Kriegs, H. |0 P:(DE-Juel1)130773 |b 2 |
700 | 1 | _ | |a Dhont, J. K. G. |0 P:(DE-Juel1)130616 |b 3 |u fzj |
700 | 1 | _ | |a Kang, K. |0 P:(DE-Juel1)130749 |b 4 |e Corresponding author |
773 | _ | _ | |a 10.1122/8.0000400 |g Vol. 66, no. 2, p. 365 - 373 |0 PERI:(DE-600)1461060-7 |n 2 |p 365 - 373 |t Journal of rheology |v 66 |y 2022 |x 0148-6055 |
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