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@ARTICLE{Ji:908064,
author = {Ji, Wenhai and Huang, Zhongyuan and Kentzinger, Emmanuel
and Rücker, Ulrich and Brückel, Thomas and Xiao, Yinguo},
title = {{N}anoparticle-induced morphological transformation in
block copolymer-based nanocomposites},
journal = {Nanoscale},
volume = {14},
number = {24},
issn = {2040-3364},
address = {Cambridge},
publisher = {RSC Publ.},
reportid = {FZJ-2022-02351},
pages = {8766-8775},
year = {2022},
abstract = {By controlling the chemical composition and the spatial
organization of nanoparticles, hybrid nanocomposites
incorporating ordered arrangements of nanoparticles could be
endowed with exotic physical and chemical properties to
fulfill demands in advanced electronics or energy-harvesting
devices. However, a simple method to fabricate hybrid
nanocomposites with precise control of nanoparticle
distribution is still challenging. We demonstrate that block
copolymer-based nanocomposites containing well-ordered
nanoparticles with various morphologies can be readily
obtained by adjusting the nanoparticle concentration.
Moreover, the structural evolution of nanocomposite thin
films as a function of nanoparticle loading is unveiled
using grazing-incidence transmission small-angle X-ray
scattering and atomic force microscopy. The morphological
transformation proceeds through a phase transition from
perforated lamellae to in-plane cylinder layout, followed by
structural changes. The successful achievement of a variety
of morphologies represents an effective and straightforward
approach to producing functional hybrid nanocomposites for
potential applications in various functional devices.},
cin = {JCNS-2 / PGI-4 / JARA-FIT},
ddc = {600},
cid = {I:(DE-Juel1)JCNS-2-20110106 / I:(DE-Juel1)PGI-4-20110106 /
$I:(DE-82)080009_20140620$},
pnm = {632 - Materials – Quantum, Complex and Functional
Materials (POF4-632) / 6G4 - Jülich Centre for Neutron
Research (JCNS) (FZJ) (POF4-6G4)},
pid = {G:(DE-HGF)POF4-632 / G:(DE-HGF)POF4-6G4},
typ = {PUB:(DE-HGF)16},
pubmed = {35674291},
UT = {WOS:000807581900001},
doi = {10.1039/D2NR01625G},
url = {https://juser.fz-juelich.de/record/908064},
}