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@INPROCEEDINGS{Meulenberg:908210,
author = {Meulenberg, Wilhelm Albert and Deibert, Wendelin and
Wolter, Julia Lucia and Nikolay, D. and Pelka, A. and
Schunk, S. and Jevtovikj, I. and Fritsch, C.},
title = {{T}he {P}roton {C}onducting {M}embrane in the {P}roject
“{A}dditive {M}anufacturing for {Z}ero-{E}mission
{I}nnovative {G}reen {C}hemistry” - {AMAZING}},
reportid = {FZJ-2022-02461},
year = {2022},
abstract = {The aim of the AMAZING project is to demonstrate the
potential of a catalytic membrane reactor process to be
developed for the dehydrogenation of small olefins while
reducing the emission of climate-damaging gases and
maintaining its economic attractiveness compared to
benchmarks of conventional processes. Therefore, the
technical objectives of the project are the production and
technical proof of function of a membrane reactor system for
the non-oxidative dehydrogenation of alkanes to unsaturated
hydrocarbons. A membrane reactor offers the possibility of
carrying out a separation process via a membrane and a
chemical reaction in direct spatial proximity. This creates
the potential for improved by-product utilisation - in this
case hydrogen. The membrane reactor can be heated with the
help of renewable energy sources. Compared to conventional
fossil-fuel heated reactor systems (ethane cracker or
catalytic propane dehydrogenation), such a reactor
technology has the potential to almost completely clean up
the CO2 footprint and to deliver "green" hydrogen as a
by-product, which can be used as a material within existing
or yet to be created composite structures. In order to
realise a functioning proton conducting membrane reactor,
robust membrane systems are required, which must be made of
ceramic materials due to the desired environmental
conditions. Tape casting is selected as the manufacturing
process and 3D printing as an innovative development.
Subsequently, a suitable technology for the insertion of a
catalyst as well as the sealing of the membrane within the
newly developed membrane reactor test stand must be
realised.This work shows the objectives of the AMAZING
project. The membranes are manufactured by tape-casting and
different additive manufacturing routes. As starting
material lanthanum tungstate with Mo-substitution is
selected. The selected additive manufacturing routes for the
supports are 3D-screen printing and material extrusion. The
membranes are characterized and tested in application
realted environments.The AMAZING project (funding code
03EN2052A, 03EN2052B and 03EN2052C) is funded by the German
Ministry of Economics and Enery and is being carried out by
the partners hte, BASF, Forschungszentrum Jülich and WZR
ceramic solutions. The German project works closely with the
cooperation partners of the project of the same name, which
is funded in the Netherlands from „ Stichting TKI-ISPT“
Dutch partners are Dow Chemicals, SHELL, University of
Eindhoven, University of Twente and Institute for
Sustainable Process Technology ISPT.},
month = {Jun},
date = {2022-06-08},
organization = {6th International Workshop "Prospects
on Protonic Ceramic Cells" PPCC2022,
Dijon (France), 8 Jun 2022 - 10 Jun
2022},
subtyp = {After Call},
cin = {IEK-1},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {1232 - Power-based Fuels and Chemicals (POF4-123)},
pid = {G:(DE-HGF)POF4-1232},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/908210},
}