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| 001 | 908253 | ||
| 005 | 20240712113006.0 | ||
| 024 | 7 | _ | |a 10.1002/ente.202200343 |2 doi |
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| 100 | 1 | _ | |a Braun, Katharina |0 0000-0003-2985-8484 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Energetics of Technical Integration of 2‐Propanol Fuel Cells: Thermodynamic and Current and Future Technical Feasibility |
| 260 | _ | _ | |a Weinheim [u.a.] |c 2022 |b Wiley-VCH |
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| 520 | _ | _ | |a 2-Propanol/acetone is a promising liquid organic hydrogen carrier system for fuelcell reactions. Herein, six different concepts for a 2-propanol/acetone fuel cellsystem are evaluated in MATLAB simulation with respect to their thermodynamicintegration and technical feasibility. Four of the concepts use a direct 2-propanolfuel cell while the other two first release molecular hydrogen from 2-propanol andsubsequently use a hydrogen fuel cell. The presented liquid phase 2-propanol fuelcell concept is thermodynamically feasible but cannot be realized technicallyusing commercial Nafion membranes, due to membrane dissolution by the2-propanol/acetone/water fuel mixture. Gaseous 2-propanol fuel cells imply a highheating requirement for the evaporation of the fuel. A direct high-temperature fuelcell using 2-propanol is thermodynamically feasible because there is less water inthe overall system but is not technically feasible because of the esterification ofphosphoric acid. A very interesting option is the conversion of gaseous 2-propanolto pressurized hydrogen in an electrochemical pumping step followed by ahydrogen fuel cell, because here the waste heat of a sufficiently hot hydrogen fuelcell can drive the 2-propanol evaporation. |
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| 773 | _ | _ | |a 10.1002/ente.202200343 |g p. 2200343 - |0 PERI:(DE-600)2700412-0 |n 8 |p 2200343 - |t Energy technology |v 10 |y 2022 |x 2194-4288 |
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