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000908323 037__ $$aFZJ-2022-02542
000908323 041__ $$aEnglish
000908323 1001_ $$0P:(DE-Juel1)129617$$aIvanova, Mariya$$b0$$eCorresponding author$$ufzj
000908323 1112_ $$a6th International Workshop Prospects on Proton Ceramic Cells$$cDijon$$d2022-06-07 - 2022-06-10$$gPPCC 2022$$wFrance
000908323 245__ $$aEffect of sintering conditions on the phase and microstructure features of Ba1.015Zr0.8-xCe0.2YxO3-δ proton conducting cell components
000908323 260__ $$c2022
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000908323 520__ $$aCeramic proton conductors of the type Ba1.015Zr0.8-xCe0.2YxO3-δ (BZCY) where x = 0.175 and 0.24 were prepared via a modified reactive solid state synthesis route from stoichiometric mixtures of BaCO3 and the corresponding oxides under addition of minor amount of NiO as a sintering aid. Ba excess of 1.5 mol. % was added to compensate possible Ba evaporation during the thermal treatments as reported previously. From the pre-heated powders half-cell assemblies consisting of a BZCY solid electrolyte layer on BZCY:NiO anode support were prepared via tape casting and compared after sintering at various conditions to reference pellets with equivalent compositions and prepared under similar conditions. The aim was to correlate the phase and microstructure features of the BZCY electrolyte layer to the presence of a supporting NiO rich layer and thus providing optimal parameters for sintering of such bi-layers with homogeneous phase composition, i.e. minimization of the secondary phase shares, and finally, proving the hypothesis that the BZCY:NiO anode composite is potentially much stronger sink for BaO than the gas phase.
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000908323 7001_ $$0P:(DE-Juel1)187594$$aSchäfer, Laura-Alena$$b1$$ufzj
000908323 7001_ $$0P:(DE-Juel1)190723$$aZeng, Yuan$$b2$$ufzj
000908323 7001_ $$0P:(DE-Juel1)144923$$aDeibert, Wendelin$$b3$$ufzj
000908323 7001_ $$0P:(DE-Juel1)129636$$aMenzler, Norbert H.$$b4$$ufzj
000908323 7001_ $$0P:(DE-Juel1)161591$$aGuillon, Olivier$$b5$$ufzj
000908323 8564_ $$uhttps://juser.fz-juelich.de/record/908323/files/Ivanova%20PPCC%202022%20Dijon.2.pdf$$yOpenAccess
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000908323 9141_ $$y2022
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