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000908610 1001_ $$0P:(DE-HGF)0$$aGiroto, Amanda S.$$b0
000908610 245__ $$aZinc loading in urea-formaldehyde nanocomposites increases nitrogen and zinc micronutrient fertilization efficiencies in poor sand substrate
000908610 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2022
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000908610 520__ $$aAgricultural output needs significant increases to feed the growing population. Fertilizers are essential for plant production systems, with nitrogen (N) being the most limiting nutrient for plant growth. It is commonly supplied to crops as urea. Still, due to volatilization, up to 50 % of the total N application is lost. Slow or controlled release fertilizers are being developed to reduce these losses. The co-application of zinc (Zn) as a micronutrient can increase N absorption. Thus, we hypothesize that the controlled delivery of both nutrients (N and Zn) in an integrated system can improve uptake efficiency. Here we demonstrate an optimized fertilizer nanocomposite based on urea:urea-formaldehyde matrix loaded with ZnSO4 or ZnO. This nanocomposite effectively stimulates maize development, with consequent adequate N uptake, in an extreme condition – a very nutrient-poor sand substrate. Our results indicate that the Zn co-application is beneficial for plant development. However, there were advantages for ZnO due to its high Zn content. We discuss that the dispersion favors the Zn delivery as the nanoparticulated oxide in the matrix. Concerning maize development, we found that root morphology is altered in the presence of the fertilizer nanocomposite. Increased root length and surface area may improve soil nutrient uptake, potentially accompanied by increased root exudation of essential compounds for N release from the composite structure.
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000908610 7001_ $$0P:(DE-HGF)0$$ado Valle, Stella F.$$b1
000908610 7001_ $$0P:(DE-HGF)0$$aGuimarães, Gelton G. F.$$b2
000908610 7001_ $$0P:(DE-Juel1)173996$$aWuyts, Nathalie$$b3$$ufzj
000908610 7001_ $$0P:(DE-Juel1)179231$$aOhrem, Benedict$$b4$$ufzj
000908610 7001_ $$0P:(DE-Juel1)129475$$aJablonowski, Nicolai David$$b5$$eCorresponding author$$ufzj
000908610 7001_ $$0P:(DE-HGF)0$$aRibeiro, Caue$$b6$$eCorresponding author
000908610 7001_ $$0P:(DE-HGF)0$$aMattoso, Luiz Henrique C.$$b7
000908610 773__ $$0PERI:(DE-600)1498726-0$$a10.1016/j.scitotenv.2022.156688$$gVol. 841, p. 156688 -$$p156688 -$$tThe science of the total environment$$v841$$x0048-9697$$y2022
000908610 8564_ $$uhttps://juser.fz-juelich.de/record/908610/files/Giroto_EtAl_2022_STOTEN_Manuscript_Zinc%20loading%20in%20Urea-Formaldehyde%20Nanocomposites%20Increases%20Nitrogen%20and%20Zinc.DOCX$$yPublished on 2022-06-15. Available in OpenAccess from 2024-06-15.
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000908610 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Embrapa Instrumentação, National Nanotechnology Laboratory for Agribusiness (LNNA), XV Novembro Street, CP: 741, 13560-206 São Carlos, SP, Brazil$$b0
000908610 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Embrapa Instrumentação, National Nanotechnology Laboratory for Agribusiness (LNNA), XV Novembro Street, CP: 741, 13560-206 São Carlos, SP, Brazil$$b1
000908610 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Federal University of São Carlos, Department of Chemistry, Washington Luiz Highway, km 235, 13565-905 São Carlos, SP, Brazil$$b1
000908610 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Agricultural Research and Rural Extension Company of Santa Catarina, 6800 Highway, Antônio Heil, Itajaí, Santa Catarina 88318112, Brazil$$b2
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000908610 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Embrapa Instrumentação, National Nanotechnology Laboratory for Agribusiness (LNNA), XV Novembro Street, CP: 741, 13560-206 São Carlos, SP, Brazil$$b6
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