Gast ::
| Hauptseite > Publikationsdatenbank > Investigation of the protolytic equilibrium of a highly Brønsted acidic ionic liquid and residual water using Raman spectroscopy > print |
| Hauptseite > Publikationsdatenbank > Investigation of the protolytic equilibrium of a highly Brønsted acidic ionic liquid and residual water using Raman spectroscopy > print |
| 001 | 908769 | ||
| 005 | 20240709082033.0 | ||
| 024 | 7 | _ | |a 10.1016/j.molliq.2021.117796 |2 doi |
| 024 | 7 | _ | |a 0167-7322 |2 ISSN |
| 024 | 7 | _ | |a 1873-3166 |2 ISSN |
| 024 | 7 | _ | |a 2128/31537 |2 Handle |
| 024 | 7 | _ | |a WOS:000713883900016 |2 WOS |
| 037 | _ | _ | |a FZJ-2022-02825 |
| 082 | _ | _ | |a 540 |
| 100 | 1 | _ | |a Chen, Yingzhen |0 P:(DE-Juel1)180579 |b 0 |u fzj |
| 245 | _ | _ | |a Investigation of the protolytic equilibrium of a highly Brønsted acidic ionic liquid and residual water using Raman spectroscopy |
| 260 | _ | _ | |a New York, NY [u.a.] |c 2022 |b Elsevier |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1658497026_6966 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a Protic ionic liquids (PILs) are promising candidates as non-aqueous proton-conducting electrolytes for use in polymer electrolyte membrane fuel cells with operating temperatures over 100 °C. 2-sulfoethylammonium triflate [2-Sea][TfO] is one such PIL electrolyte, in which the highly Brønsted acidic sulfoalkylammonium cations act as mobile protonic charge carriers and proton donors. In order to gain a molecular-level understanding of proton transfer in a PIL electrolyte containing a small amount of residual water from fuel cell operation, the protolytic equilibrium of the highly acidic cation was investigated by means of Raman spectroscopy. Density functional theory (DFT) calculations were conducted to identify the vibration modes sensitive to protonation and to gain information on the possible conformation of the cation. The deprotonation of the 2-sulfoethylammonium cation resulted in a characteristic upward frequency shift in the ν(SC) stretching vibration. An equilibrium constant of 0.23 ± 0.09 was calculated for the protolytic reaction, indicating [2-Sea][TfO] as a promising proton donor for the fuel cell application. |
| 536 | _ | _ | |a 1231 - Electrochemistry for Hydrogen (POF4-123) |0 G:(DE-HGF)POF4-1231 |c POF4-123 |f POF IV |x 0 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
| 700 | 1 | _ | |a Endres, Manuel B. |0 P:(DE-Juel1)166532 |b 1 |
| 700 | 1 | _ | |a Giffin, Jürgen |0 P:(DE-Juel1)129938 |b 2 |u fzj |
| 700 | 1 | _ | |a Korte, Carsten |0 P:(DE-Juel1)140525 |b 3 |e Corresponding author |u fzj |
| 773 | _ | _ | |a 10.1016/j.molliq.2021.117796 |g Vol. 345, p. 117796 - |0 PERI:(DE-600)1491496-7 |p 117796 - |t Journal of molecular liquids |v 345 |y 2022 |x 0167-7322 |
| 856 | 4 | _ | |y Published on 2021-10-12. Available in OpenAccess from 2023-10-12. |u https://juser.fz-juelich.de/record/908769/files/Manuscript_Protolytic%20Equilibrium_k20211001.pdf |
| 856 | 4 | _ | |y Published on 2021-10-12. Available in OpenAccess from 2023-10-12. |u https://juser.fz-juelich.de/record/908769/files/SupplementaryMaterial_202101013.pdf |
| 909 | C | O | |o oai:juser.fz-juelich.de:908769 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 0 |6 P:(DE-Juel1)180579 |
| 910 | 1 | _ | |a RWTH Aachen |0 I:(DE-588b)36225-6 |k RWTH |b 0 |6 P:(DE-Juel1)180579 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 2 |6 P:(DE-Juel1)129938 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 3 |6 P:(DE-Juel1)140525 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Energie |l Materialien und Technologien für die Energiewende (MTET) |1 G:(DE-HGF)POF4-120 |0 G:(DE-HGF)POF4-123 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-100 |4 G:(DE-HGF)POF |v Chemische Energieträger |9 G:(DE-HGF)POF4-1231 |x 0 |
| 914 | 1 | _ | |y 2022 |
| 915 | _ | _ | |a Embargoed OpenAccess |0 StatID:(DE-HGF)0530 |2 StatID |
| 915 | _ | _ | |a WoS |0 StatID:(DE-HGF)0113 |2 StatID |b Science Citation Index Expanded |d 2021-02-03 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0160 |2 StatID |b Essential Science Indicators |d 2021-02-03 |
| 915 | _ | _ | |a Nationallizenz |0 StatID:(DE-HGF)0420 |2 StatID |d 2022-11-18 |w ger |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2022-11-18 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2022-11-18 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2022-11-18 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2022-11-18 |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b J MOL LIQ : 2021 |d 2022-11-18 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2022-11-18 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0600 |2 StatID |b Ebsco Academic Search |d 2022-11-18 |
| 915 | _ | _ | |a Peer Review |0 StatID:(DE-HGF)0030 |2 StatID |b ASC |d 2022-11-18 |
| 915 | _ | _ | |a IF >= 5 |0 StatID:(DE-HGF)9905 |2 StatID |b J MOL LIQ : 2021 |d 2022-11-18 |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-14-20191129 |k IEK-14 |l Elektrochemische Verfahrenstechnik |x 0 |
| 980 | 1 | _ | |a FullTexts |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-14-20191129 |
| 981 | _ | _ | |a I:(DE-Juel1)IET-4-20191129 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|