% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Khnle:908795,
      author       = {Kühnle, Hannes and Knobbe, Edwin and Figgemeier, Egbert},
      title        = {{I}n {S}itu {O}ptical and {E}lectrochemical
                      {I}nvestigations of {L}ithium {D}epositions as a {F}unction
                      of {C}urrent {D}ensities},
      journal      = {Journal of the Electrochemical Society},
      volume       = {169},
      number       = {4},
      issn         = {0013-4651},
      address      = {Bristol},
      publisher    = {IOP Publishing},
      reportid     = {FZJ-2022-02840},
      pages        = {040528 -},
      year         = {2022},
      abstract     = {The electrodeposition behavior of lithium metal as a
                      function of the current density at room temperature was
                      investigated in a symmetrical face‑to‑face in‑situ
                      optical cell. After a defined initial contact time between
                      electrode and electrolyte, various current densities in the
                      range of 0.05 mA cm−2 to 10 mA cm−2 were tested.
                      Constant current phases, electrochemical impedance
                      spectroscopy measurements and in situ images of the working
                      electrode were recorded and results were compared. Two
                      regimes of lithium deposition with different optical and
                      electrochemical characteristics were identified as a
                      function of current density. The first regime, at low
                      current densities (0.05 mA cm−2–0.5 mA cm−2), showed
                      none to tiny lithium depositions with sporadic large lithium
                      structures at the higher end of this range. The second
                      regime, at high current densities (2 mA cm−2–10 mA
                      cm−2), showed many smaller, deposited lithium structures.
                      The experimental results are discussed in the context of the
                      formation and presence of metal-electrolyte interphases
                      presumably by chemical reactions between lithium and
                      electrolyte, current density and their interactions with
                      each other. The correlation of fundamental parameters of
                      lithium metal deposition with current density must be taken
                      into account for the development of lithium metal-based
                      energy storage devices.},
      cin          = {IEK-12},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000782495000001},
      doi          = {10.1149/1945-7111/ac644e},
      url          = {https://juser.fz-juelich.de/record/908795},
}