TY  - JOUR
AU  - Wolf, Stephanie E.
AU  - Vibhu, Vaibhav
AU  - Tröster, Eric
AU  - Vinke, Izaak C.
AU  - Eichel, Rüdiger-A.
AU  - de Haart, L. G. J.
TI  - Steam Electrolysis vs. Co-Electrolysis: Mechanistic Studies of Long-Term Solid Oxide Electrolysis Cells
JO  - Energies
VL  - 15
IS  - 15
SN  - 1996-1073
CY  - Basel
PB  - MDPI
M1  - FZJ-2022-02891
SP  - 5449
PY  - 2022
AB  - High-temperature electrolysis using solid oxide electrolysis cells (SOECs) is an innovative technology to temporarily store unused electrical energy from renewable energy sources. However, they show continuous performance loss during long-term operation, which is the main issue preventing their widespread use. In this work, we have performed the long-term stability tests up to 1000 h under steam and co-electrolysis conditions using commercial NiO-YSZ/YSZ/GDC/LSC single cells in order to understand the degradation process. The electrolysis tests were carried out at different temperatures and fuel gas compositions. Intermittent AC- and DC- measurements were performed to characterize the single cells and to determine the responsible electrode processes for the degradation during long-term operation. An increased degradation rate is observed at 800°C compared to 750°C under steam electrolysis conditions. Moreover, a lower degradation rate is noticed under co-electrolysis operation in comparison to steam electrolysis operation. Finally, the post-test analyses using SEM-EDX and XRD were carried out in order to understand the degradation mechanism. The delamination of LSC is observed under steam electrolysis conditions at 800°C, however, such delamination is not observed during co-electrolysis operation. In addition, Ni-depletion and agglomeration are observed on the fuel electrode side for all the cells.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000839683000001
DO  - DOI:10.3390/en15155449
UR  - https://juser.fz-juelich.de/record/908877
ER  -