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@ARTICLE{Prause:909071,
      author       = {Prause, Albert and Hechenbichler, Michelle and von
                      Lospichl, Benjamin and Feoktystov, Artem and Schweins, Ralf
                      and Mahmoudi, Najet and Laschewsky, André and Gradzielski,
                      Michael},
      title        = {{A}ggregation {B}ehavior of {N}onsymmetrically
                      {E}nd-{C}apped {T}hermoresponsive {B}lock {C}opolymers in
                      {A}queous {S}olutions: {B}etween {P}olymer {C}oils and
                      {M}icellar {S}tates},
      journal      = {Macromolecules},
      volume       = {55},
      number       = {13},
      issn         = {0024-9297},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2022-02989},
      pages        = {5849 - 5863},
      year         = {2022},
      abstract     = {The thermosensitive aggregation behavior in an aqueous
                      solution of a library of amphiphilic BAB* copolymers is
                      studied, where “A” represents a long permanently
                      hydrophilic poly(N,N-dimethylacrylamide) (pDMAm) block,
                      “B” represents a permanently hydrophobic end with an
                      n-dodecyl chain, and “B*” represents a thermoresponsive
                      (TR) block featuring a lower critical solution temperature
                      (LCST). Four polyacrylamides are employed for B*, namely,
                      poly(N-n-propylacrylamide) (pNPAm),
                      poly(N-isopropylacrylamide) (pNiPAm),
                      poly(N,N-diethylacrylamide) (pDEAm), and
                      poly(N-acryloylpyrrolidine) (pNAP), which differ with
                      respect to the hydrophilicity of their amide side chains and
                      LCST behavior. While blocks A and B were kept constant, the
                      lengths of the TR blocks were varied systematically. These
                      amphiphilic copolymers were studied as a function of
                      concentration and temperature via light and neutron
                      scattering (static light scattering (SLS), dynamic light
                      scattering (DLS), small-angle neutron scattering (SANS)).
                      For sufficiently long pNiPAM and pDEAm blocks (DPn > 40), a
                      pronounced hydrophobic effect at temperatures above the LCST
                      transition results in well-structured, ordered aggregates.
                      Thus, the aggregation can be controlled by the choice and
                      length of the TR block, thereby elucidating a so far hardly
                      explored class of temperature-sensitive polymeric
                      amphiphiles.},
      cin          = {JCNS-FRM-II / MLZ / JCNS-1 / JCNS-4},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3 /
                      I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)JCNS-4-20201012},
      pnm          = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
                      (POF4-6G4) / 632 - Materials – Quantum, Complex and
                      Functional Materials (POF4-632)},
      pid          = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-632},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000823879800001},
      doi          = {10.1021/acs.macromol.2c00878},
      url          = {https://juser.fz-juelich.de/record/909071},
}