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@ARTICLE{Overstreet:909075,
author = {Overstreet, Cale and Cooper, Jacob and O'Quinn, Eric and
Cureton, William and Palomares, Raul and Leys, Julia and
Deissmann, Guido and Neumeier, Stefan and Chen, Chien-Hung
and Lang, Maik},
title = {{S}tructural stability of {REE}-{PO}4 ({REE} = {S}m,{T}b)
under swift heavy ion irradiation},
journal = {Nuclear instruments $\&$ methods in physics research / B},
volume = {527},
issn = {0168-583X},
address = {Amsterdam [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2022-02993},
pages = {34 - 39},
year = {2022},
abstract = {Rare earth element (REE) phosphates are an attractive host
matrix for long-lived radionuclides from nuclear waste
because of the radiation tolerance exhibited by naturally
occurring REE phosphate specimens. Here we show that SmPO4
(monazite structure) and TbPO4 (xenotime structure) exhibit
a similar amorphization response to swift heavy ion
irradiation despite different starting structures. SmPO4 and
TbPO4 were irradiated with 1.1 GeV Au ions and analyzed
using synchrotron-based X-ray diffraction (XRD), Raman
spectroscopy, and transmission electron microscopy (TEM).
The radiation response of the phosphates was evaluated by
extracting the amorphous fraction at each irradiation
fluence, and a single-impact model was used to determine the
amorphous cross section and track diameter. Amorphization
within individual ion tracks was confirmed using head-on TEM
imaging, and the amorphous track size agreed with the value
deduced by XRD analysis. Raman measurements were performed
to qualitatively confirm the ion-induced
crystalline-to-amorphous transformation which proceeds
similarly for both phosphates.},
cin = {IEK-6},
ddc = {530},
cid = {I:(DE-Juel1)IEK-6-20101013},
pnm = {1411 - Nuclear Waste Disposal (POF4-141)},
pid = {G:(DE-HGF)POF4-1411},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000874682100005},
doi = {10.1016/j.nimb.2022.07.014},
url = {https://juser.fz-juelich.de/record/909075},
}