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024 7 _ |a 10.1016/j.nimb.2022.07.014
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100 1 _ |a Overstreet, Cale
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245 _ _ |a Structural stability of REE-PO4 (REE = Sm,Tb) under swift heavy ion irradiation
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520 _ _ |a Rare earth element (REE) phosphates are an attractive host matrix for long-lived radionuclides from nuclear waste because of the radiation tolerance exhibited by naturally occurring REE phosphate specimens. Here we show that SmPO4 (monazite structure) and TbPO4 (xenotime structure) exhibit a similar amorphization response to swift heavy ion irradiation despite different starting structures. SmPO4 and TbPO4 were irradiated with 1.1 GeV Au ions and analyzed using synchrotron-based X-ray diffraction (XRD), Raman spectroscopy, and transmission electron microscopy (TEM). The radiation response of the phosphates was evaluated by extracting the amorphous fraction at each irradiation fluence, and a single-impact model was used to determine the amorphous cross section and track diameter. Amorphization within individual ion tracks was confirmed using head-on TEM imaging, and the amorphous track size agreed with the value deduced by XRD analysis. Raman measurements were performed to qualitatively confirm the ion-induced crystalline-to-amorphous transformation which proceeds similarly for both phosphates.
536 _ _ |a 1411 - Nuclear Waste Disposal (POF4-141)
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700 1 _ |a Cooper, Jacob
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700 1 _ |a O'Quinn, Eric
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700 1 _ |a Cureton, William
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700 1 _ |a Palomares, Raul
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700 1 _ |a Leys, Julia
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700 1 _ |a Deissmann, Guido
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700 1 _ |a Neumeier, Stefan
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700 1 _ |a Chen, Chien-Hung
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700 1 _ |a Lang, Maik
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773 _ _ |a 10.1016/j.nimb.2022.07.014
|g Vol. 527, p. 34 - 39
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|t Nuclear instruments & methods in physics research / B
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856 4 _ |u https://juser.fz-juelich.de/record/909075/files/Overstreet%20NIMB%202022.pdf
|y Published on 2022-08-06. Available in OpenAccess from 2024-08-06.
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