000909121 001__ 909121 000909121 005__ 20240712113255.0 000909121 0247_ $$2doi$$a10.1021/acsami.2c01302 000909121 0247_ $$2ISSN$$a1944-8244 000909121 0247_ $$2ISSN$$a1944-8252 000909121 0247_ $$2Handle$$a2128/31678 000909121 0247_ $$2pmid$$a35452215 000909121 0247_ $$2WOS$$aWOS:000812960400001 000909121 037__ $$aFZJ-2022-03021 000909121 082__ $$a600 000909121 1001_ $$0P:(DE-Juel1)175127$$aXia, Lu$$b0$$ufzj 000909121 245__ $$aMultistep Sulfur Leaching for the Development of a Highly Efficient and Stable NiS x /Ni(OH) 2 /NiOOH Electrocatalyst for Anion Exchange Membrane Water Electrolysis 000909121 260__ $$aWashington, DC$$bSoc.$$c2022 000909121 3367_ $$2DRIVER$$aarticle 000909121 3367_ $$2DataCite$$aOutput Types/Journal article 000909121 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1662355347_21700 000909121 3367_ $$2BibTeX$$aARTICLE 000909121 3367_ $$2ORCID$$aJOURNAL_ARTICLE 000909121 3367_ $$00$$2EndNote$$aJournal Article 000909121 520__ $$aNickel (poly)sulfides have been widely studied as anodic catalysts for alkaline water electrolysis owing to their diverse morphologies, high catalytic activities in the oxygen evolution reaction (OER), and low cost. To utilize low-cost and high-efficiency polysulfides with industry-relevant cycling stability, we develop a Ni-rich NiSx/Ni(OH)2/NiOOH catalyst derived from NiS2/Ni3S4 nanocubes. Ni-rich NiSx/Ni(OH)2/NiOOH shows improved OER catalytic activity (η = 374 mV@50 mA cm–2) and stability (0.1% voltage increase) after 65 h of a galvanostatic test at 10 mA cm–2 compared with commercial Ni/NiO and hydrothermally synthesized Ni(OH)2 (both show η > 460 mV@50 mA cm–2 along with 4.40 and 1.92% voltage increase, respectively). A water-splitting electrolyzer based on Pt/C||AF1-HNN8-50||NiSx/Ni(OH)2/NiOOH exhibits a current density of 1800 mA cm–2 at 2.0 V and 500 h high-rate stability at 1000 mA cm–2 with negligible attenuation of only 0.12 mV h–1. This work provides an understanding of truly stable species, intrinsic active phases of Ni polysulfides, their high-rate stability in a real cell, and sheds light on the development of stable chalcogenide-based anodic electrocatalysts for anion exchange membrane water electrolysis (AEMWE). 000909121 536__ $$0G:(DE-HGF)POF4-1231$$a1231 - Electrochemistry for Hydrogen (POF4-123)$$cPOF4-123$$fPOF IV$$x0 000909121 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de 000909121 7001_ $$0P:(DE-HGF)0$$aJiang, Wulyu$$b1 000909121 7001_ $$0P:(DE-Juel1)166271$$aHartmann, Heinrich$$b2$$ufzj 000909121 7001_ $$0P:(DE-Juel1)130824$$aMayer, Joachim$$b3$$ufzj 000909121 7001_ $$0P:(DE-Juel1)129883$$aLehnert, Werner$$b4$$ufzj 000909121 7001_ $$0P:(DE-Juel1)165174$$aShviro, Meital$$b5$$eCorresponding author 000909121 773__ $$0PERI:(DE-600)2467494-1$$a10.1021/acsami.2c01302$$gVol. 14, no. 17, p. 19397 - 19408$$n17$$p19397 - 19408$$tACS applied materials & interfaces$$v14$$x1944-8244$$y2022 000909121 8564_ $$uhttps://juser.fz-juelich.de/record/909121/files/Invoice_APC600307029.pdf 000909121 8564_ $$uhttps://juser.fz-juelich.de/record/909121/files/acsami.2c01302.pdf$$yOpenAccess 000909121 8767_ $$8APC600307029$$92022-04-11$$aBelegnr. 1200180185$$d2022-04-13$$eHybrid-OA$$jZahlung erfolgt$$zUSD 3750,- 000909121 909CO $$ooai:juser.fz-juelich.de:909121$$pdnbdelivery$$popenCost$$pVDB$$pdriver$$pOpenAPC$$popen_access$$popenaire 000909121 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)175127$$aForschungszentrum Jülich$$b0$$kFZJ 000909121 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-Juel1)175127$$aRWTH Aachen$$b0$$kRWTH 000909121 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-HGF)0$$aForschungszentrum Jülich$$b1$$kFZJ 000909121 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-HGF)0$$aRWTH Aachen$$b1$$kRWTH 000909121 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166271$$aForschungszentrum Jülich$$b2$$kFZJ 000909121 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130824$$aForschungszentrum Jülich$$b3$$kFZJ 000909121 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)129883$$aForschungszentrum Jülich$$b4$$kFZJ 000909121 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-Juel1)129883$$aRWTH Aachen$$b4$$kRWTH 000909121 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)165174$$aForschungszentrum Jülich$$b5$$kFZJ 000909121 9131_ $$0G:(DE-HGF)POF4-123$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1231$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vChemische Energieträger$$x0 000909121 9141_ $$y2022 000909121 915__ $$0LIC:(DE-HGF)CCBYNCND4$$2HGFVOC$$aCreative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0 000909121 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2021-01-30 000909121 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess 000909121 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2021-01-30 000909121 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2022-11-11 000909121 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2022-11-11 000909121 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2022-11-11 000909121 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology$$d2022-11-11 000909121 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2022-11-11 000909121 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2022-11-11 000909121 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bACS APPL MATER INTER : 2021$$d2022-11-11 000909121 915__ $$0StatID:(DE-HGF)9910$$2StatID$$aIF >= 10$$bACS APPL MATER INTER : 2021$$d2022-11-11 000909121 920__ $$lyes 000909121 9201_ $$0I:(DE-Juel1)IEK-14-20191129$$kIEK-14$$lElektrochemische Verfahrenstechnik$$x0 000909121 9201_ $$0I:(DE-Juel1)ZEA-3-20090406$$kZEA-3$$lAnalytik$$x1 000909121 9201_ $$0I:(DE-Juel1)ER-C-2-20170209$$kER-C-2$$lMaterialwissenschaft u. 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