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@PHDTHESIS{ZHOU:909349,
author = {ZHOU, Wenyu},
title = {{M}echanical properties of single and dual phase proton
conducting membranes},
volume = {584},
school = {Univ. Twente},
type = {Dissertation},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2022-03139},
isbn = {978-3-95806-645-8},
series = {Schriften des Forschungszentrums Jülich Reihe Energie $\&$
Umwelt / Energy $\&$ Environment},
pages = {IV, VI, 133},
year = {2022},
note = {Dissertation, Univ. Twente, 2022},
abstract = {Dual-phase hydrogen permeation membranes, consisting of
protonic and electronic conducting phases, shows great
potential for high purity hydrogen production due to its
high stability in harsh applications. Hydrogen-ion
conductive perovskite phases (e.g. BaCe0.65Zr0.2Y0.15O3-δ)
and electron conductive fluorite oxides (e.g.
Ce0.85Gd0.15O2-δ) are promising candidate for this biphasic
hydrogen transport membrane. Mechanical properties (e.g.
elastic modulus, hardness, fracture toughness) of the
membranes are essential parameters regarding the reliability
of subsequent applications. These parameters are closely
related to microstructural features such as grain size,
phase distribution and defects (e.g. pores and microcracks).
However, these relationships are not yet fully understood.
Therefore, in this thesis, the effects of grain size,
phasedistribution, pores and microcracks on mechanical
properties are investigated for BaCe0.65Zr0.2Y0.15O3-δ and
BaCe0.65Zr0.2Y0.15O3-δ-Ce0.85Gd0.15O2-δ membranes.
Material preparation procedures (e.g. milling and sintering)
are optimized to overcome the difficulty in material
preparation.},
cin = {IEK-2},
cid = {I:(DE-Juel1)IEK-2-20101013},
pnm = {899 - ohne Topic (POF4-899)},
pid = {G:(DE-HGF)POF4-899},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
url = {https://juser.fz-juelich.de/record/909349},
}