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@ARTICLE{Scheld:909447,
author = {Scheld, Walter Sebastian and Lobe, Sandra and Dellen,
Christian and Ihrig, Martin and Häuschen, Grit and Hoff,
Linda Charlotte and Finsterbusch, Martin and Uhlenbruck,
Sven and Guillon, Olivier and Fattakhova-Rohlfing, Dina},
title = {{R}apid thermal processing of garnet-based composite
cathodes},
journal = {Journal of power sources},
volume = {545},
issn = {0378-7753},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2022-03194},
pages = {231872 -},
year = {2022},
abstract = {Rapid thermal annealing techniques enable quick and
non-contact processing of ceramic materials and are
particularly promising for materials containing elements
with high vapor pressure. For example, Li-ion conductive
oxide-ceramics such as the garnet-type Li7La3Zr2O12 (LLZO)
need to be densified in order to be used as separators or in
composite cathodes of all-solid-state batteries (ASB), but
suffer from lithium loss at elevated temperatures. To
address this issue, the sintering method “rapid thermal
processing” (RTP) is used to fabricate ceramic composite
cathodes of LLZO and LiCoO2 (LCO), the cathode active
material. The cathodes were deposited on LLZO separators by
screen-printing, a scalable industrial process for the
fabrication of ceramic components. A detailed analysis by
Raman spectroscopy and X-ray diffraction analysis confirms
the successful mitigation of secondary phase formation
between LCO and LLZO. The subsequent application of In-metal
anodes resulted in fully inorganic ASB that were
electrochemically cycled.},
cin = {IEK-1},
ddc = {620},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {1223 - Batteries in Application (POF4-122) /
Verbundprojekt: OptiKeraLyt: Material- und
Produktionsprozessoptimierung für Lithium-Ionen-Batterien
mit keramischen Festkörperelektrolyten; Teilvorhaben:
Synthese von keramischen Festkörperkomponenten (03ETE016F)
/ CatSe - Interfaces and Interphases in Rechargeable Li
Based Batteries: Cathode/Solid Electrolyte (13XP0223A) /
FestBatt-Oxide - Materialplattform 'Oxide' im Rahmen des
Kompetenzclusters für Festkörperbatterien (13XP0173A)},
pid = {G:(DE-HGF)POF4-1223 / G:(BMWi)03ETE016F / G:(BMBF)13XP0223A
/ G:(BMBF)13XP0173A},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000862785300004},
doi = {10.1016/j.jpowsour.2022.231872},
url = {https://juser.fz-juelich.de/record/909447},
}