% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Yang:909498,
      author       = {Yang, Xiaosheng and Jugovac, Matteo and Zamborlini,
                      Giovanni and Feyer, Vitaliy and Koller, Georg and Puschnig,
                      Peter and Soubatch, Serguei and Ramsey, Michael G. and
                      Tautz, F. Stefan},
      title        = {{M}omentum-selective orbital hybridisation},
      journal      = {Nature Communications},
      volume       = {13},
      number       = {1},
      issn         = {2041-1723},
      address      = {[London]},
      publisher    = {Nature Publishing Group UK},
      reportid     = {FZJ-2022-03204},
      pages        = {5148},
      year         = {2022},
      abstract     = {When a molecule interacts chemically with a metal surface,
                      the orbitals of the molecule hybridise with metal states to
                      form the new eigenstates of the coupled system. Spatial
                      overlap and energy matching are determining parameters of
                      the hybridisation. However, since every molecular orbital
                      does not only have a characteristic spatial shape, but also
                      a specific momentum distribution, one may additionally
                      expect a momentum matching condition; after all, each
                      hybridising wave function of the metal has a defined wave
                      vector, too. Here, we report photoemission orbital
                      tomography measurements of hybrid orbitals that emerge from
                      molecular orbitals at a molecule-on-metal interface. We find
                      that in the hybrid orbitals only those partial waves of the
                      original orbital survive which match the metal band
                      structure. Moreover, we find that the conversion of the
                      metal’s surface state into a hybrid interface state is
                      also governed by momentum matching constraints. Our
                      experiments demonstrate the possibility to measure
                      hybridisation momentum-selectively, thereby enabling deep
                      insights into the complicated interplay of bulk states,
                      surface states, and molecular orbitals in the formation of
                      the electronic interface structure at molecule-on-metal
                      hybrid interfaces.},
      cin          = {PGI-3},
      ddc          = {500},
      cid          = {I:(DE-Juel1)PGI-3-20110106},
      pnm          = {5213 - Quantum Nanoscience (POF4-521)},
      pid          = {G:(DE-HGF)POF4-5213},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {36055995},
      UT           = {WOS:000849365000007},
      doi          = {10.1038/s41467-022-32643-z},
      url          = {https://juser.fz-juelich.de/record/909498},
}