Home > Publications database > New route to amide-functionalized N-donor ligands enables improved selective solvent extraction of trivalent actinides > print

001     909579
005     20240712084555.0
024 7 _ |a 10.1039/D2CC03876E
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024 7 _ |a 0009-241X
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024 7 _ |a 0022-4936
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024 7 _ |a 1359-7345
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024 7 _ |a 1364-548X
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024 7 _ |a 2050-5620
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024 7 _ |a 2050-5639
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024 7 _ |a 2128/31898
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024 7 _ |a 36063119
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082 _ _ |a 540
100 1 _ |a Bulmer, Rachel
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245 _ _ |a New route to amide-functionalized N-donor ligands enables improved selective solvent extraction of trivalent actinides
260 _ _ |a Cambridge
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520 _ _ |a A new general synthetic route to selective actinide extractingligands for spent nuclear fuel reprocessing has been established.The amide-functionalized ligands separate Am(III) and Cm(III) fromthe lanthanides with high selectivities and show rapid rates of metalextraction. The ligands retain the advantages of the analogousunfunctionalized ligands derived from camphorquinone, whilstalso negating their main drawback; precipitate formation when incontact with nitric acid. These studies could enable the design ofimproved solvent extraction processes for closing the nuclearfuel cycle.
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700 1 _ |a Spencer, Thomas B.
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700 1 _ |a Wilden, Andreas
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700 1 _ |a Modolo, Giuseppe
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700 1 _ |a Vu, Trong-Hung
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700 1 _ |a Simonin, Jean-Pierre
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700 1 _ |a Lewis, Frank W.
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773 _ _ |a 10.1039/D2CC03876E
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913 1 _ |a DE-HGF
|b Forschungsbereich Energie
|l Nukleare Entsorgung, Sicherheit und Strahlenforschung (NUSAFE II)
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914 1 _ |y 2022
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