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@INPROCEEDINGS{Park:909889,
author = {Park, Gunwoo and Naegele, Gerhard},
title = {{T}he effect of shear-induced migration on crossflow
filtration of colloids},
reportid = {FZJ-2022-03497},
year = {2022},
abstract = {Membrane crossflow filtration is widely used for the
enrichment and purification of colloidal and protein
dispersions. In this pressure-driven process, a feed
dispersion is steadily pumped through a channel consisting
of solvent-permeable membrane walls. The applied
transmembrane pressure (TMP) causes advection of the
dispersion toward the membrane, and formation of a
particle-enriched diffuse layer near its surface. This
so-called concentration polarization (CP) layer increases
the osmotic particle pressure counteracting the TMP. When
the particle concentration reaches a solidification limit,
an immobilized particulate layer, termed cake layer, is
formed next to the membrane surface. The cake layer adds to
the hydraulic membrane resistance and lowers thus the
filtration efficiency. A key problem is to understand
quantitatively how cake formation is related to filtration
operating conditions, and to dispersion and membrane
properties. In this study, we theoretically analyze how
permeate flux and cake layer formation are influenced by the
size, charge and feed concentration of dispersed particles
[1]. We consider dispersions of neutral and
charge-stabilized colloidal particles. Under conditions
where shear-induced migration matters, empirical expressions
for shear-rate dependent transport properties are used. Our
results for concentration and flow profiles under filtration
are obtained using a recently developed modified boundary
layer approximation (mBLA) method [2, 3]. The mBLA is a
numerically efficient and accurate method for predicting
filtration properties. A thorough dicussion of the so-called
critical permeate flux related to the onset of cake layer
formation is presented. Moreover, an analytic expression for
the critical flux is derived and compared with standard
predictions by film theory and mass transfer coefficient
calculations. References[1] G. W. Park, J. K. G. Dhont, and
G. Nägele, manuscript in preparation.[2] G. W. Park and G.
Nägele, Journal of Chemical Physics, 2020, 153, 204110[3]
G. W. Park and G. Nägele, Membranes, 2021, 11, 960},
month = {Sep},
date = {2022-09-19},
organization = {International Soft Matter Conference
2022, Poznan (Poland), 19 Sep 2022 - 23
Sep 2022},
subtyp = {After Call},
cin = {IBI-4},
cid = {I:(DE-Juel1)IBI-4-20200312},
pnm = {5241 - Molecular Information Processing in Cellular Systems
(POF4-524)},
pid = {G:(DE-HGF)POF4-5241},
typ = {PUB:(DE-HGF)6},
url = {https://juser.fz-juelich.de/record/909889},
}