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@ARTICLE{Li:910146,
author = {Li, Xinfang and Groß-Barsnick, Sonja M. and Baumann,
Stefan and Koppitz, Thomas and Meulenberg, Wilhelm A. and
Natour, Ghaleb},
title = {{T}hermal properties and joinability investigation of
{B}a{O}–{S}r{O}–{S}i{O} 2 –{B} 2 {O} 3 glasses for
oxygen transport membrane application},
journal = {Advanced engineering materials},
volume = {24},
number = {12},
issn = {1438-1656},
address = {Frankfurt, M.},
publisher = {Deutsche Gesellschaft für Materialkunde},
reportid = {FZJ-2022-03635},
pages = {2200660},
year = {2022},
abstract = {Three new BaO–SrO–SiO2–B2O3 (BS) glasses with
different SrO contents $(6–25 mol\%)$ are developed for
oxygen transport membrane (OTM) joining application. The
content of strontium is investigated first in terms of its
effect on the glass-forming tendency, thermal expansion
coefficient, crystallization, shrinkage behavior, and
viscous flow properties. Differential scanning calorimetry
(DSC) is carried out. Dilatometric tests are performed to
obtain coefficients of thermal expansion (CTEs) of BS
glasses. The crystallization behavior of the BS glasses is
investigated by X-ray powder diffraction (XRD). Sinking
dilatometric measurements simulate the joining procedure and
observe the shrinkage behavior of the BS glasses. The
viscous flow behavior of the BS glasses is examined via hot
stage microscopy. The glass with $15 mol\%$ SrO (BS15)
glass shows the best glass-forming tendency, most matching
CTE (11.9 × 10−6 K−1), densest microstructure,
highest shrinkage rate $(24\%),$ and good viscous behavior
at high joining temperatures compared with other BS glasses.
BS15 glass is chosen for helium leak test and assembly test
joining with Aluchrom and SrTi0.75Fe0.25O3−δ membrane
(STF25). The sandwiched sample with two Aluchrom plates
sealed by BS15 glass at 1075 °C for 5 min achieves good
gas-tightness with low helium leakage rate
<10−9 mbar·l s−1.},
cin = {IEK-1 / ZEA-1},
ddc = {660},
cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)ZEA-1-20090406},
pnm = {1232 - Power-based Fuels and Chemicals (POF4-123)},
pid = {G:(DE-HGF)POF4-1232},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000870538300001},
doi = {10.1002/adem.202200660},
url = {https://juser.fz-juelich.de/record/910146},
}