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@ARTICLE{Uhlenbruck:910178,
      author       = {Uhlenbruck, Sven},
      title        = {{A} {P}hysical {D}erivation of the {C}apacitive {B}rick
                      {L}ayer {M}odel in {P}olycrystalline {C}eramics from
                      {F}undamental {E}lectrodynamic {E}quations},
      journal      = {Journal of the Electrochemical Society},
      volume       = {169},
      number       = {10},
      issn         = {0013-4651},
      address      = {Bristol},
      publisher    = {IOP Publishing},
      reportid     = {FZJ-2022-03658},
      pages        = {106509 , 5 pages},
      year         = {2022},
      abstract     = {The brick layer model in electrochemical impedance
                      spectroscopy has been successfully used for decades to
                      describe the behaviorof polycrystalline materials.
                      Equivalent circuits were created to obtain information about
                      grain and grain boundary properties fromelectrochemical
                      impedance spectroscopy measurements. Previous publications
                      have expanded on initial interpretations anddescribed grains
                      and grain boundaries as plate capacitors filled with the
                      grain and grain boundary material, respectively.
                      However,this approach poses a number of significant issues,
                      since key assumptions for the equivalent circuits do not
                      match with the actualexperimental situation of the material
                      when exposed to an outer electric field, thus calling into
                      question the entire approach for theinterpretation.},
      cin          = {IEK-1 / IEK-12},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000867412600001},
      doi          = {10.1149/1945-7111/ac96b0},
      url          = {https://juser.fz-juelich.de/record/910178},
}