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@ARTICLE{Deo:910219,
author = {Deo, Meenal and Möllmann, Alexander and Haddad, Jinane and
Ünlü, Feray and Kulkarni, Ashish and Liu, Maning and
Tachibana, Yasuhiro and Stadler, Daniel and Bhardwaj, Aman
and Ludwig, Tim and Kirchartz, Thomas and Mathur, Sanjay},
title = {{T}antalum {O}xide as an {E}fficient {A}lternative
{E}lectron {T}ransporting {L}ayer for {P}erovskite {S}olar
{C}ells},
journal = {Nanomaterials},
volume = {12},
number = {5},
issn = {2079-4991},
address = {Basel},
publisher = {MDPI},
reportid = {FZJ-2022-03696},
pages = {780 -},
year = {2022},
abstract = {Electron transporting layers facilitating electron
extraction and suppressing hole recombination at the cathode
are crucial components in any thin-film solar cell geometry,
including that of metal–halide perovskite solar cells.
Amorphous tantalum oxide (Ta2O5) deposited by spin coating
was explored as an electron transport material for
perovskite solar cells, achieving power conversion
efficiency (PCE) up to $~14\%.$ Ultraviolet photoelectron
spectroscopy (UPS) measurements revealed that the extraction
of photogenerated electrons is facilitated due to proper
alignment of bandgap energies. Steady-state
photoluminescence spectroscopy (PL) verified efficient
charge transport from perovskite absorber film to thin Ta2O5
layer. Our findings suggest that tantalum oxide as an n-type
semiconductor with a calculated carrier density of ~7 ×
1018/cm3 in amorphous Ta2O5 films, is a potentially
competitive candidate for an electron transport material in
perovskite solar cells},
cin = {IEK-5},
ddc = {540},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {1212 - Materials and Interfaces (POF4-121)},
pid = {G:(DE-HGF)POF4-1212},
typ = {PUB:(DE-HGF)16},
pubmed = {35269269},
UT = {WOS:000768477000001},
doi = {10.3390/nano12050780},
url = {https://juser.fz-juelich.de/record/910219},
}