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@ARTICLE{Weling:910340,
      author       = {Weßling, Patrik and Maag, Melina and Baruth, Giana and
                      Sittel, Thomas and Sauerwein, Fynn S. and Wilden, Andreas
                      and Modolo, Giuseppe and Geist, Andreas and Panak, Petra J.},
      title        = {{C}omplexation and {E}xtraction {S}tudies of {T}rivalent
                      {A}ctinides and {L}anthanides with {W}ater-{S}oluble and
                      {CHON}-{C}ompatible {L}igands for the {S}elective
                      {E}xtraction of {A}mericium},
      journal      = {Inorganic chemistry},
      volume       = {61},
      number       = {44},
      issn         = {0020-1669},
      address      = {Washington, DC},
      publisher    = {American Chemical Society},
      reportid     = {FZJ-2022-03759},
      pages        = {17719–17729},
      year         = {2022},
      abstract     = {Novel hydrophilic ligands to selectively separate Am(III)
                      are synthesized:
                      3,3′-([2,2′-bipyridine]-6,6′-diylbis(1H-1,2,3-triazole-4,1-diyl))bis(propan-1-ol)
                      (PrOH-BPTD) and
                      3,3′-([2,2′-bipyridine]-6,6′-diylbis(1H-1,2,3-triazole-4,1-diyl))bis(ethan-1-ol)
                      (EtOH-BPTD). The complexation of An(III) and Ln(III) with
                      PrOH- and EtOH-BPTD is studied by time-resolved laser
                      fluorescence spectroscopy. [ML2]3+ is found for both Cm(III)
                      and Eu(III), while [ML]3+ is only formed with Cm(III).
                      Stability constants show a preferential coordination of
                      Cm(III) over Eu(III) with PrOH-BPTD being the stronger
                      ligand. The distribution of Am(III), Cm(III), and Ln(III)
                      between an organic phase containing the extracting agent
                      N,N,N′,N′-tetra-n-octyl-3-oxapentanediamide (TODGA) and
                      aqueous phases containing PrOH-BPTD is studied as a function
                      of time and temperature as well as the TODGA, BPTD, and HNO3
                      concentrations. A system composed of 0.2 mol/L TODGA and
                      0.04 mol/L PrOH-BPTD in 0.33–0.39 mol/L HNO3 allows for
                      selective Am(III) back-extraction into the aqueous phase
                      while keeping Cm(III) and Ln(III) in the organic phase,
                      marking PrOH-BPTD as an excellent complexant for an
                      optimized AmSel process (Am(III) selective extraction).},
      cin          = {IEK-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-6-20101013},
      pnm          = {1412 - Predisposal (POF4-141) / PATRICIA - Partitioning And
                      Transmuter Research Initiative in a Collaborative Innovation
                      Action (945077) / BMBF-02NUK059D - Spektroskopische
                      Charakterisierung von f-Element-Komplexen mit soft
                      donor-Liganden (f-Char) (BMBF-02NUK059D)},
      pid          = {G:(DE-HGF)POF4-1412 / G:(EU-Grant)945077 /
                      G:(DE-Juel1)BMBF-02NUK059D},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {36274232},
      UT           = {WOS:000877103700001},
      doi          = {10.1021/acs.inorgchem.2c02871},
      url          = {https://juser.fz-juelich.de/record/910340},
}