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@ARTICLE{Kulikovsky:910624,
author = {Kulikovsky, Andrei},
title = {{E}ffect of proton conductivity transients on {PEM} fuel
cell impedance: {F}ormation of a low–frequency inductive
loop},
journal = {Electrochemistry communications},
volume = {140},
issn = {1388-2481},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2022-04002},
pages = {107340 -},
year = {2022},
abstract = {A model for PEMFC cathode impedance is developed. The model
includes transient response of catalyst layer proton
conductivity to cell current density variation. Analytical
solution shows that transient conductivity leads to
formation of a low–frequency inductive loop in the Nyquist
spectrum. This loop has been observed in numerous
experiments and its nature has long been discussed in
literature. The results of this work provide a new mechanism
of loop formation},
cin = {IEK-13},
ddc = {540},
cid = {I:(DE-Juel1)IEK-13-20190226},
pnm = {1231 - Electrochemistry for Hydrogen (POF4-123)},
pid = {G:(DE-HGF)POF4-1231},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000891239800009},
doi = {10.1016/j.elecom.2022.107340},
url = {https://juser.fz-juelich.de/record/910624},
}