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@ARTICLE{Yalcinkaya:910809,
author = {Yalcinkaya, Hacer and Mangiapia, Gaetano and Appavou,
Marie-Sousai and Hoffmann, Ingo and Gradzielski, Michael},
title = {{P}olymeric {N}anocapsules from {W}ell-{D}efined
{Z}witanionic {V}esicles as a {T}emplate},
journal = {Macromolecules},
volume = {55},
number = {17},
issn = {0024-9297},
address = {Washington, DC},
publisher = {Soc.},
reportid = {FZJ-2022-04161},
pages = {7869 - 7878},
year = {2022},
abstract = {Polymeric nanocapsules have application in versatile
fields, thus they have drawn much attention in the past
decade. Preparing a homogeneous, uniform, small nanocapsule
system is challenging and requires further improvement. A
powerful way for realizing controlled synthesis of these
submicron structures is by initiating them from a vesicular
basis. Herein, we report the formation of highly
monodisperse and rather small polymeric nanocapsules
originating from a well-defined self-assembled
surfactant-based system. In our approach, a monomer is
initially dissolved in surfactant micelles, which are
transformed spontaneously into well-defined vesicles upon
mixing with a second surfactant solution. Subsequently, the
monomer-loaded vesicles become polymerized via UV-initiated
polymerization, where different amounts of monomers and
cross-linkers are employed. The whole process is
characterized in detail by light scattering and small-angle
neutron scattering (SLS, DLS, and SANS) analyses. The final
product of small, unilamellar, highly monodisperse polymeric
nanocapsules has potential for applications with entrapping
the cargo either in the aqueous core or in the hydrophobic
membrane.},
cin = {JCNS-4 / JCNS-1 / JCNS-FRM-II / MLZ},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-4-20201012 / I:(DE-Juel1)JCNS-1-20110106 /
I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ)
(POF4-6G4) / 632 - Materials – Quantum, Complex and
Functional Materials (POF4-632)},
pid = {G:(DE-HGF)POF4-6G4 / G:(DE-HGF)POF4-632},
experiment = {EXP:(DE-MLZ)KWS1-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000848470800001},
doi = {10.1021/acs.macromol.2c01023},
url = {https://juser.fz-juelich.de/record/910809},
}