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@ARTICLE{Sieg:910827,
author = {Sieg, Johannes and Schmid, Alexander U. and Rau, Laura and
Gesterkamp, Andreas and Storch, Mathias and Spier, Bernd and
Birke, Kai Peter and Sauer, Dirk Uwe},
title = {{F}ast-charging capability of lithium-ion cells:
{I}nfluence of electrode aging and electrolyte consumption},
journal = {Applied energy},
volume = {305},
issn = {0306-2619},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2022-04177},
pages = {117747 -},
year = {2022},
abstract = {Fast charging of electric vehicles is becoming more and
more important for achieving customer acceptance of
electromobility. During fast charging, the maximum charging
rate of the lithium-ion cells used in the traction batteries
of electric vehicles has to be controlled properly to avoid
the deposition of metallic lithium on the surface of the
negative electrode, known as lithium plating. However, cycle
life tests have shown that after a few hundred cycles at a
moderate aging rate, the fast-charging capability of
lithium-ion cells decreases and a sudden, rapid loss of
capacity is observable. Therefore, to achieve a long service
life and, concurrently, short charging times, it is crucial
to analyze the non-plating critical charging rate depending
on the mode of battery degradation.In this paper, we
separately investigate the influence of the main aging
factors, such as electrode aging and electrolyte
consumption, on the fast-charging capability of large-format
automotive lithium-ion pouch cells. The pouch cells are
cycled to different states of health and a post-mortem local
degradation analysis is performed. Using three-electrode
test cells, the non-plating critical charging curves are
determined for the aged electrode material and for test
cells assembled with different amounts of electrolyte. Our
findings reveal that for the investigated lithium-ion pouch
cells the fast-charging capability is reduced over cycling
not by the aging of the electrodes but by the consumption of
electrolyte.},
cin = {IEK-12 / JARA-ENERGY},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217 / $I:(DE-82)080011_20140620$},
pnm = {1223 - Batteries in Application (POF4-122)},
pid = {G:(DE-HGF)POF4-1223},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000703605700003},
doi = {10.1016/j.apenergy.2021.117747},
url = {https://juser.fz-juelich.de/record/910827},
}