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@PHDTHESIS{Perla:911176,
author = {Perla, Pujitha},
title = {{G}rowth and characterization of {I}n{A}s nanowire-based
{J}osephson junctions},
school = {RWTH Aachen},
type = {Dissertation},
publisher = {RWTH Aachen University},
reportid = {FZJ-2022-04488},
pages = {126 p},
year = {2022},
note = {Dissertation, RWTH Aachen, 2022},
abstract = {This work delves into the growth mechanism as well as
structural and electrical characterization of InAs nanowires
(NWs) for Josephson junctions. The superconductors used in
this case are aluminum and niobium. Josephson junctions are
an essential component of a superconducting qubit. This work
describes the evolution of the Josephson junctions within
the state-of-the-art and achieving higher transparency of
the semiconductor/superconductor interfaces. The first part
of the work deals with the optimization of the selective
area growth. This method offers greater control of the
growth of nanowires and provides higher uniformity.
Parameters such as temperature, indium growth rate, and
arsenic beam equivalent pressure (BEP) have been optimized
to achieve a growth yield of $95\%,$ using a 20 nm thick
silicon dioxide mask on a Si(111) substrate. Eventually, the
InAs nanowires are grown and optimized for diameters of
70-80 nm and lengths of 4-5 μm. Additional experiments have
been performed to dope the InAs nanowires with tellurium. In
the case of Josephson junctions, they offer a huge asset,
with a doping range of 1× $10^18$ $cm^−3$ to 1× $10^19$
$cm^−3.$ An increase in the conductance of these nanowires
is observed with increased doping and thereby an enhanced
critical current of the Josephson junctions. Moreover, Te
doping has shown an impact on the diameter and the length of
the nanowires, since it is a surfactant. Atom probe
tomography investigations performed on these nanowires show
additional (211) lateral facets, that shift the hexagonal
structure of the InAs nanowire to a partly dodecagon
structure at Te doping concentrations greater than
$1×10^19$ $cm^−3.$ Furthermore, the transparency of the
InAs/superconductor interface has been tuned. A defect-free
interface and a smooth film of a superconductor is
apre-requisite for a high-quality Josephson junction, since
this ensures a good coupling between the materials. A
complete in-situ method has been adopted, to grow Al and Nb,
onto the nanowires, thereby eliminating, any possible
exposure of the semiconductor surface to the ambient. To
achieve defect-free semiconductor/superconductor interfaces,
a brief degassing step is introduced to the nanowires before
the growth of the superconducting metals such as aluminum or
niobium. This process, ensured enhanced transparency between
the materials, thereby strengthening the coupling, by that
improving the proximity effect. To be brief, the proximity
effect induces Cooper pairs into the semiconductor, i.e. it
turns the NW partly into a superconductor. Furthermore, the
growth parameters of the metals evaporated are optimized to
produce a smooth and defect-free interface and are
investigated systematically. Lastly, the in-situ approach is
expanded to encompass the fabrication of Josephson junctions
at ultra-high vacuum conditions and to include other
superconducting and capping materials in the process. The
substrates made for this purpose have been prepared in such
a way that two nanowires grow in a square trench at 90° to
the planes of the trench. The growth windows for the NW
growth are meticulously and selectively placed in such a way
that one NW shadows the other during the metal evaporation,
thus, causing a junction on the latter wire. The
superconductors used in this process are optimized to create
smooth and defect-free layers. In the case of aluminum, the
growth of the metals is found to depend more on the
temperature than on the angle of deposition. In contrast,
for Nb, the angle of evaporation has a huge effect on the
smoothness of the film. The investigations presented in
these sections include transmission electron microscopy and
corresponding low-temperature electrical measurements. This
shadow approach, increased the metal evaporation angles onto
the nanowires, from 30° to 87°, thus causing smooth and
defect-free layers. This has also been shown to increase the
interface transparency, between the NW and the
superconductors. Lastly, this platform has also been used to
demonstrate the growth of complex NW networks and multiple
Josephson junctions.},
keywords = {nanowires (Other)},
cin = {PGI-9},
cid = {I:(DE-Juel1)PGI-9-20110106},
pnm = {5222 - Exploratory Qubits (POF4-522)},
pid = {G:(DE-HGF)POF4-5222},
typ = {PUB:(DE-HGF)11},
doi = {10.18154/RWTH-2022-08606},
url = {https://juser.fz-juelich.de/record/911176},
}