TY - JOUR
AU - Wang, Lina
AU - Song, Qizhen
AU - Pei, Fengtao
AU - Chen, Yihua
AU - Dou, Jie
AU - Wang, Hao
AU - Shi, Congbo
AU - Zhang, Xiao
AU - Fan, Rundong
AU - Zhou, Wentao
AU - Qiu, Zhiwen
AU - Kang, Jiaqian
AU - Wang, Xueyun
AU - Lambertz, Andreas
AU - Sun, Mengru
AU - Niu, Xiuxiu
AU - Ma, Yue
AU - Zhu, Cheng
AU - Zhou, Huanping
AU - Hong, Jiawang
AU - Bai, Yang
AU - Duan, Weiyuan
AU - Ding, Kaining
AU - Chen, Qi
TI - Strain Modulation for Light‐Stable n–i–p Perovskite/Silicon Tandem Solar Cells
JO - Advanced materials
VL - 34
IS - 26
SN - 0935-9648
CY - Weinheim
PB - Wiley-VCH
M1 - FZJ-2022-04510
SP - 2201315 -
PY - 2022
AB - Perovskite/silicon tandem solar cells are promising to penetrate photovoltaicmarket. However, the wide-bandgap perovskite absorbers used in top-celloften suffer severe phase segregation under illumination, which restricts theoperation lifetime of tandem solar cells. Here, a strain modulation strategyto fabricate light-stable perovskite/silicon tandem solar cells is reported. Byemploying adenosine triphosphate, the residual tensile strain in the wide-bandgapperovskite absorber is successfully converted to compressive strain,which mitigates light-induced ion migration and phase segregation. Basedon the wide-bandgap perovskite with compressive strain, single-junctionsolar cells with the n–i–p layout yield a power conversion efficiency (PCE) of20.53% with the smallest voltage deficits of 440 mV. These cells also maintain83.60% of initial PCE after 2500 h operation at the maximum power point.Finally, these top cells are integrated with silicon bottom cells in a monolithictandem device, which achieves a PCE of 26.95% and improved light stabilityat open-circuit.
LB - PUB:(DE-HGF)16
C6 - 35435280
UR - <Go to ISI:>//WOS:000796547500001
DO - DOI:10.1002/adma.202201315
UR - https://juser.fz-juelich.de/record/911204
ER -