TY - JOUR
AU - Qiu, Depeng
AU - Duan, Weiyuan
AU - Lambertz, Andreas
AU - Eberst, Alexander
AU - Bittkau, Karsten
AU - Rau, Uwe
AU - Ding, Kaining
TI - Transparent Conductive Oxide Sputtering Damage on Contact Passivation in Silicon Heterojunction Solar Cells with Hydrogenated Nanocrystalline Silicon
JO - Solar RRL
VL - 6
IS - 10
SN - 2367-198X
CY - Weinheim
PB - Wiley-VCH
M1 - FZJ-2022-04511
SP - 2200651
PY - 2022
AB - Mitigating the adverse effect of transparent conductive oxide (TCO) sputtering onthe passivation quality of the heterojunction contact is very critical for achievinghigh-efficiency silicon heterojunction (SHJ) solar cells. Herein, n-type ultra-thin(5 nm) nanocrystalline silicon (nc-Si:H) is utilized as a contact layer in rear-junctionSHJ solar cells. It is revealed that the TCO sputtering damage on the contact layer iscaused by the ion bombardment during the sputtering process and cannot be fullyrecovered by low-temperature annealing. A more severe passivation deteriorationis observed for the devices with nc-Si:H(n) having a higher microstructure factor.This result is explained by an increased ion penetration depth in the porous nc-Si:Hfilm. By applying denser nc-Si:H(n) in SHJ solar cells, the front silicon film stackshows more resilience to sputter damage, yielding a remarkable cell performanceon the M2-size wafer with certificated power conversion efficiency (η) of 23.87%.The sputter damage on nc-Si:H by TCO in SHJ solar cells is explored in depth forthe first time from the perspective of silicon thin films.
LB - PUB:(DE-HGF)16
UR - <Go to ISI:>//WOS:000845082600001
DO - DOI:10.1002/solr.202200651
UR - https://juser.fz-juelich.de/record/911205
ER -