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@ARTICLE{Qiu:911205,
author = {Qiu, Depeng and Duan, Weiyuan and Lambertz, Andreas and
Eberst, Alexander and Bittkau, Karsten and Rau, Uwe and
Ding, Kaining},
title = {{T}ransparent {C}onductive {O}xide {S}puttering {D}amage on
{C}ontact {P}assivation in {S}ilicon {H}eterojunction
{S}olar {C}ells with {H}ydrogenated {N}anocrystalline
{S}ilicon},
journal = {Solar RRL},
volume = {6},
number = {10},
issn = {2367-198X},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2022-04511},
pages = {2200651},
year = {2022},
abstract = {Mitigating the adverse effect of transparent conductive
oxide (TCO) sputtering onthe passivation quality of the
heterojunction contact is very critical for
achievinghigh-efficiency silicon heterojunction (SHJ) solar
cells. Herein, n-type ultra-thin(5 nm) nanocrystalline
silicon (nc-Si:H) is utilized as a contact layer in
rear-junctionSHJ solar cells. It is revealed that the TCO
sputtering damage on the contact layer iscaused by the ion
bombardment during the sputtering process and cannot be
fullyrecovered by low-temperature annealing. A more severe
passivation deteriorationis observed for the devices with
nc-Si:H(n) having a higher microstructure factor.This result
is explained by an increased ion penetration depth in the
porous nc-Si:Hfilm. By applying denser nc-Si:H(n) in SHJ
solar cells, the front silicon film stackshows more
resilience to sputter damage, yielding a remarkable cell
performanceon the M2-size wafer with certificated power
conversion efficiency (η) of $23.87\%.The$ sputter damage
on nc-Si:H by TCO in SHJ solar cells is explored in depth
forthe first time from the perspective of silicon thin
films.},
cin = {IEK-5},
ddc = {600},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {1213 - Cell Design and Development (POF4-121) /
Verbundvorhaben: Street - Einsatz von hocheffizienten
Solarzellen in elektrisch betriebenen Nutzfahrzeugen;
Teilvorhaben: Herstellung und Entwicklung von (0324275E) /
Verbundvorhaben: TuKaN - Tunnelkontakte auf N-Typ: für die
Metallisierung mit Siebdruck, Teilvorhaben: Herstellung von
Solarzellen mit passivierendem Tunnelkontakt und
funktionalen Schichten aus katalytischer und
plasmaunterstützter chemischer Gasphasenab (0324198D) /
Touch - Technologie- und Charakterisierungsplattform für
die Entwicklung von hoch-effizienten
Silizium-Heterostruktursolarzellen (0324351)},
pid = {G:(DE-HGF)POF4-1213 / G:(BMWi)0324275E / G:(BMWi)0324198D /
G:(BMWi)0324351},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000845082600001},
doi = {10.1002/solr.202200651},
url = {https://juser.fz-juelich.de/record/911205},
}