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000911476 1001_ $$0P:(DE-Juel1)171715$$aKretzschmar, Ansgar$$b0$$eCorresponding author
000911476 245__ $$aApplication of a tailorable carbon molecular sieve to evaluate concepts for the molecular dimensions of gases
000911476 260__ $$aAmsterdam [u.a.]$$bElsevier$$c2022
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000911476 520__ $$aMolecular sieves have attracted considerable interest for gas separation applications due to their ability todiscriminate substances by their molecule’s size. To predict if a molecular sieve is suitable for a specific separationproblem an accurate measure of the molecular sizes is called for. Furthermore, a high precision in estimationsfor molecular dimensions is needed for the characterization of materials using molecular probes. In thiswork, different popular concepts to estimate the size of a gas molecule, specifically Breck’s kinetic diameter, thecritical diameter and molecular dimensions by Webster (MIN-1) are discussed. These concepts are evaluatedusing a tailorable carbon molecular sieve. It is concluded, that the widely used kinetic diameter has somedrawbacks to determine the accessibility of pores. Finally, recommendations for alternatives from existingliterature are presented.
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000911476 536__ $$0G:(GEPRIS)390919832$$aEXC 2186:  The Fuel Science Center – Adaptive Conversion Systems for Renewable Energy and Carbon Sources (390919832)$$c390919832$$x1
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000911476 7001_ $$0P:(DE-Juel1)178824$$aSelmert, Victor$$b1
000911476 7001_ $$0P:(DE-Juel1)157700$$aKungl, Hans$$b2$$ufzj
000911476 7001_ $$0P:(DE-Juel1)161208$$aTempel, Hermann$$b3$$ufzj
000911476 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b4$$ufzj
000911476 773__ $$0PERI:(DE-600)2012505-7$$a10.1016/j.micromeso.2022.112156$$gVol. 343, p. 112156 -$$p112156 -$$tMicroporous and mesoporous materials$$v343$$x1387-1811$$y2022
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