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@ARTICLE{Kretzschmar:911476,
      author       = {Kretzschmar, Ansgar and Selmert, Victor and Kungl, Hans and
                      Tempel, Hermann and Eichel, Rüdiger-A.},
      title        = {{A}pplication of a tailorable carbon molecular sieve to
                      evaluate concepts for the molecular dimensions of gases},
      journal      = {Microporous and mesoporous materials},
      volume       = {343},
      issn         = {1387-1811},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2022-04747},
      pages        = {112156 -},
      year         = {2022},
      abstract     = {Molecular sieves have attracted considerable interest for
                      gas separation applications due to their ability
                      todiscriminate substances by their molecule’s size. To
                      predict if a molecular sieve is suitable for a specific
                      separationproblem an accurate measure of the molecular sizes
                      is called for. Furthermore, a high precision in
                      estimationsfor molecular dimensions is needed for the
                      characterization of materials using molecular probes. In
                      thiswork, different popular concepts to estimate the size of
                      a gas molecule, specifically Breck’s kinetic diameter,
                      thecritical diameter and molecular dimensions by Webster
                      (MIN-1) are discussed. These concepts are evaluatedusing a
                      tailorable carbon molecular sieve. It is concluded, that the
                      widely used kinetic diameter has somedrawbacks to determine
                      the accessibility of pores. Finally, recommendations for
                      alternatives from existingliterature are presented.},
      cin          = {IEK-9},
      ddc          = {530},
      cid          = {I:(DE-Juel1)IEK-9-20110218},
      pnm          = {1232 - Power-based Fuels and Chemicals (POF4-123) / EXC
                      2186:  The Fuel Science Center – Adaptive Conversion
                      Systems for Renewable Energy and Carbon Sources (390919832)},
      pid          = {G:(DE-HGF)POF4-1232 / G:(GEPRIS)390919832},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000862789800005},
      doi          = {10.1016/j.micromeso.2022.112156},
      url          = {https://juser.fz-juelich.de/record/911476},
}