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| 001 | 911476 | ||
| 005 | 20240712112814.0 | ||
| 024 | 7 | _ | |a 10.1016/j.micromeso.2022.112156 |2 doi |
| 024 | 7 | _ | |a 1387-1811 |2 ISSN |
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| 037 | _ | _ | |a FZJ-2022-04747 |
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| 100 | 1 | _ | |a Kretzschmar, Ansgar |0 P:(DE-Juel1)171715 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Application of a tailorable carbon molecular sieve to evaluate concepts for the molecular dimensions of gases |
| 260 | _ | _ | |a Amsterdam [u.a.] |c 2022 |b Elsevier |
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| 520 | _ | _ | |a Molecular sieves have attracted considerable interest for gas separation applications due to their ability todiscriminate substances by their molecule’s size. To predict if a molecular sieve is suitable for a specific separationproblem an accurate measure of the molecular sizes is called for. Furthermore, a high precision in estimationsfor molecular dimensions is needed for the characterization of materials using molecular probes. In thiswork, different popular concepts to estimate the size of a gas molecule, specifically Breck’s kinetic diameter, thecritical diameter and molecular dimensions by Webster (MIN-1) are discussed. These concepts are evaluatedusing a tailorable carbon molecular sieve. It is concluded, that the widely used kinetic diameter has somedrawbacks to determine the accessibility of pores. Finally, recommendations for alternatives from existingliterature are presented. |
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| 700 | 1 | _ | |a Selmert, Victor |0 P:(DE-Juel1)178824 |b 1 |
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| 773 | _ | _ | |a 10.1016/j.micromeso.2022.112156 |g Vol. 343, p. 112156 - |0 PERI:(DE-600)2012505-7 |p 112156 - |t Microporous and mesoporous materials |v 343 |y 2022 |x 1387-1811 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/911476/files/Kretzschmar%2C%20Selmert%20et%20al%202022%20-%20Application%20of%20a%20tailorable%20carbon.pdf |y OpenAccess |
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