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@ARTICLE{Nikolaev:912399,
author = {Nikolaev, K. G. and Ermakov, S. S. and Ermolenko, Yu. E.
and Navolotskaya, D. V. and Offenhäusser, A. and Mourzina,
Youlia},
title = {{H}orseradish {P}eroxidase-{B}ased {B}iosensors with
{D}ifferent {N}anotransducers for the {D}etermination of
{H}ydrogen {P}eroxide},
journal = {Journal of analytical chemistry},
volume = {76},
number = {4},
issn = {1061-9348},
address = {Dordrecht [u.a.]},
publisher = {Springer Science + Business Media B.V},
reportid = {FZJ-2022-05584},
pages = {510 - 517},
year = {2021},
abstract = {We studied methods of the in situ synthesis of gold
nanostructures on the electrode surface and of the directed
electrochemical synthesis of nanodendrites to create
biosensors based on horseradish peroxidase. The effect of
nanostructuring of the transducer surface and its subsequent
modification on the electroanalytical characteristics of
sensors for the determination of hydrogen peroxide was
studied. The use of these methods can significantly improve
the performance characteristics of the biosensors, such as
the sensitivity coefficient, limit of detection, and
stability in the range of micromolar and submicromolar
concentrations of hydrogen peroxide. The electrodes modified
by the in situ synthesis of nanostructures with subsequent
treatment with Meerwein’s reagent, as well as
ultramicroelectrodes prepared by directional electrochemical
synthesis, show low limits of detection for hydrogen
peroxide, 0.2 and 0.08 µM, and high sensitivity
coefficients, 0.71 and 0.84 A M–1 cm–2, respectively.},
cin = {IBI-3},
ddc = {540},
cid = {I:(DE-Juel1)IBI-3-20200312},
pnm = {5241 - Molecular Information Processing in Cellular Systems
(POF4-524)},
pid = {G:(DE-HGF)POF4-5241},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000640197200011},
doi = {10.1134/S1061934821040080},
url = {https://juser.fz-juelich.de/record/912399},
}