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@ARTICLE{RezaieGhaleh:916052,
      author       = {Rezaie Ghaleh, Nasrollah},
      title        = {{W}ater {D}ynamics in {H}ighly {C}oncentrated {S}alt
                      {S}olutions: {A} {M}ulti‐{N}uclear {NMR} {A}pproach},
      journal      = {ChemistryOpen},
      volume       = {11},
      number       = {6},
      issn         = {2191-1355},
      address      = {Weinheim},
      publisher    = {Wiley-VCH-Verl.},
      reportid     = {FZJ-2022-05898},
      pages        = {e202200080},
      year         = {2022},
      abstract     = {Living cells often contain compartments with high
                      concentration of charged biomolecules. A key question
                      pertinent to the function of biomolecules is how water
                      dynamics are affected by interaction with charged molecules.
                      Here, we study the dynamical behavior of water in an extreme
                      condition, that is, in saturated salt solutions, where
                      nearly all water molecules are located within the first
                      hydration layer of ions. To facilitate disentangling the
                      effects of cations and anions, our study is focused on
                      alkali chloride solutions. Following a multi-nuclear NMR
                      approach enabling direct monitoring of protons and the
                      quadrupolar nuclei 7Li, 17O, 23Na, 35Cl, 87Rb and 133Cs, we
                      investigate how the translational and rotational mobility of
                      water molecules, chloride anion and corresponding cations
                      are affected within the constrained environment of saturated
                      solutions. Our results indicate that water molecules
                      preserve a large level of mobility within saturated alkali
                      chloride solutions that is significantly independent of
                      adjacent ions.},
      cin          = {IBI-7},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IBI-7-20200312},
      pnm          = {5241 - Molecular Information Processing in Cellular Systems
                      (POF4-524)},
      pid          = {G:(DE-HGF)POF4-5241},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {35642137},
      UT           = {WOS:000803753400001},
      doi          = {10.1002/open.202200080},
      url          = {https://juser.fz-juelich.de/record/916052},
}