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@ARTICLE{Kundu:916120,
author = {Kundu, Sumana and Solomatin, Nickolay and Kraytsberg,
Alexander and Ein-Eli, Yair},
title = {{M}g{S}c 2 {S}e 4 {S}olid {E}lectrolyte for {R}echargeable
{M}g {B}atteries: {A}n {E}lectric {F}ield‐{A}ssisted
{A}ll‐{S}olid‐{S}tate {S}ynthesis},
journal = {Energy technology},
volume = {10},
number = {11},
issn = {2194-4288},
address = {Weinheim [u.a.]},
publisher = {Wiley-VCH},
reportid = {FZJ-2022-05951},
pages = {2200896 -},
year = {2022},
abstract = {Magnesium scandium chalcogenide spinels are an important
class of materials in Mg anode-based batteries for energy
storage applications. The applications of these intriguing
materials are not limited to the energy storage, but the use
of these materials may also be useful in solar cells, owing
to the material optical bandgap. So far, all reported
synthetic routes for these spinels involve high-temperature
furnace treatment. Herein, a process which involves a facile
electric field-assisted synthesis of MgSc2Se4 is reported
on, yielding after a very short thermal treatment, a
material possessing a low room-temperature electronic
conductivity of ≈10−11 S cm−1, and a
room-temperature Mg-ion conductivity of
1.78 × 10−5 S cm−1. The crucial role of extra
selenium on the material electronic conductivity is
discussed and explained in detail.},
cin = {IEK-9},
ddc = {620},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {1223 - Batteries in Application (POF4-122)},
pid = {G:(DE-HGF)POF4-1223},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000857948400001},
doi = {10.1002/ente.202200896},
url = {https://juser.fz-juelich.de/record/916120},
}