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@ARTICLE{Kundu:916121,
author = {Kundu, Sumana and Kraytsberg, Alexander and Ein-Eli, Yair},
title = {{R}ecent development in the field of ceramics solid-state
electrolytes: {I}—oxide ceramic solid-state electrolytes},
journal = {Journal of solid state electrochemistry},
volume = {26},
number = {9},
issn = {1432-8488},
address = {New York},
publisher = {Springer},
reportid = {FZJ-2022-05952},
pages = {1809 - 1838},
year = {2022},
abstract = {Many elements in the periodic table form ionic compounds;
the crystal lattices of such compounds contain cations and
anions, which are arranged in the way that these cations and
anions form two interpenetrated sub-lattices (cation and
anion sub-lattices). Up to now, a number of ionic compounds
are known, in which cations or anions are fairly mobile
within the corresponding sub-lattice; these compounds are
termed as “solid-state electrolytes”. Many solid-state
electrolytes with such moveable cations and moveable anions
are known to date. Following the footsteps of the
established Li-ion battery technology, an interest in the
Li+-conducting solid-state electrolytes appears, and
all-solid-state lithium battery has started its journey to
accompany the reigning counterpart. The valence and ionic
radius of ions, the crystal structure, and intrinsic defects
of the material are the prime properties of the solid-state
electrolytes, which determine the ion mobility in the
crystal framework. There are a number of solid-state
electrolyte structures that demonstrate high Li+-mobility
and high Li+ conductivity (Li+ superconductors) in the range
of 10−2 to 10−3 S/cm at room temperature, which is
comparable to the ionic conductivity of 1 M LiPF6
(~ 10−2 S/cm), but the conductivity can dwindle highly
by up to 5–6 orders of magnitude within the different
materials that belonged to the same crystal structure
family. Moreover, the surface or interface properties are
also crucial factors in tailoring the ionic conductivity of
practical polycrystalline solid electrolytes. The
interfacial properties and compatibility with electrode
materials have a high impact on the performance of
electrochemical cells with solid electrolytes. Although the
potential window of many solid electrolytes is high enough,
there are solid electrolytes which are unstable at low
operating potentials while others are not stable towards the
cathodes; these features result in the appearance of
non-conductive interface layers resulting in a low
interfacial charge–transfer kinetics. In this review, we
discuss the latest advancements in the field of Li-ion
conducting electrolytes from the points of their fundamental
properties. The latest achievements in the fields of cell
design and improvements of (solid-state
electrolytes)/(various anodes) and (solid-state
electrolytes)/(various cathodes) compatibilities are
considered as well.},
cin = {IEK-9},
ddc = {540},
cid = {I:(DE-Juel1)IEK-9-20110218},
pnm = {1223 - Batteries in Application (POF4-122)},
pid = {G:(DE-HGF)POF4-1223},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000817847000001},
doi = {10.1007/s10008-022-05206-x},
url = {https://juser.fz-juelich.de/record/916121},
}