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000916897 0247_ $$2doi$$a10.1021/acsagscitech.2c00248
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000916897 1001_ $$00000-0001-6992-3717$$aBorges, Roger$$b0$$eCorresponding author
000916897 245__ $$aMechanochemical Activation of Elemental Sulfur Increases Its Bioavailability in the Forage Species Brachiaria Production
000916897 260__ $$aWashington, DC$$bACS Publications$$c2022
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000916897 520__ $$aAlthough sulfur is an essential macronutrient for plants, its supply through elemental S0 is not efficient, demanding its oxidation by soil microbiota before plant uptake. Thus, we demonstrate that a simple reactive mechanochemical route, using anhydrous KOH as a reactant with no need for water addition, can convert S0 to bio-absorbable oxidized forms, leading the residual K+ a plant nutrient in the final composition. The powdery products obtained by 1 h (S-1h) or 8 h (S-8h) milling have been fully converted to HSO3-, SO32-, and SO42-, also suggesting different amounts of these sulfur oxides according to the milling. S-1h and S-8h were efficient for S and K fertilization, probed on the successful growing of the forage crop Brachiaria ssp. in a greenhouse trial, with similar biomass yields observed for K2SO4 (positive control) and superior to S0 + KCl (negative control). These data suggest that the mechanochemical process provides a sustainable route to increase sulfur plant bioavailability, suggesting a simple alternative that can be easily implemented in forage plant production sites such as Brachiaria ssp.
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000916897 7001_ $$0P:(DE-HGF)0$$aSotiles, Anne Raquel$$b1
000916897 7001_ $$0P:(DE-HGF)0$$aGiroto, Amanda Soares$$b2
000916897 7001_ $$00000-0001-9029-5241$$aFernandes Guimarães, Gelton Geraldo$$b3
000916897 7001_ $$00000-0002-3498-8323$$aWypych, Fernando$$b4
000916897 7001_ $$0P:(DE-Juel1)129475$$aJablonowski, Nicolai David$$b5$$ufzj
000916897 7001_ $$0P:(DE-Juel1)177079$$aRibeiro, Caue$$b6$$eCorresponding author
000916897 773__ $$0PERI:(DE-600)3053506-2$$a10.1021/acsagscitech.2c00248$$gVol. 2, no. 6, p. 1292 - 1299$$n6$$p1292 - 1299$$tACS Agricultural science & technology$$v2$$x2692-1952$$y2022
000916897 8564_ $$uhttps://juser.fz-juelich.de/record/916897/files/Borges_EtAl_2022_Mechanochemical%20Activation%20of%20Elemental%20Sulfur%20Increases%20Its%20Bioavailability%20in%20the%20Forage%20Species%20Brachiaria%20Production.pdf$$yRestricted
000916897 8564_ $$uhttps://juser.fz-juelich.de/record/916897/files/Borges_EtAl_2022_Mechanochemical%20Activation%20of%20Elemental%20Sulfur%20Increases%20Its%20Bioavailability%20in%20the%20Forage%20Species%20Brachiaria%20Production_Supplementary_Material.pdf$$yRestricted
000916897 8564_ $$uhttps://juser.fz-juelich.de/record/916897/files/Borges_EtAl_2022_Mechanochemical%20activation%20of%20Elemental%20Sulfur%20increases%20its%20bioavailability%20in%20the%20forage%20species%20Brachiaria%20production_PostPrint.pdf$$yPublished on 2022-11-30. Available in OpenAccess from 2023-11-30.
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000916897 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Departamento de Química, Universidade Federal do Paraná, CP 19032, 81531-980 Curitiba-PR, Brazil$$b1
000916897 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Institute of Bio- and Geosciences, IBG-2: Plant Sciences, Forschungszentrum Jülich GmbH, Jülich, Germany$$b2
000916897 9101_ $$0I:(DE-HGF)0$$6P:(DE-HGF)0$$a Embrapa Instrumentation, 1452 XV de Novembro Street, São Carlos, SP, 13560-970, Brazil$$b2
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000916897 9141_ $$y2022
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