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@ARTICLE{Uhlenbruck:9223,
author = {Uhlenbruck, S. and Jordan, N. and Serra, J.M. and
Buchkremer, H. P. and Stöver, D.},
title = {{A}pplication of electrolyte layers for solid oxide fuel
cells by electron beam evaporation},
journal = {Solid state ionics},
volume = {181},
issn = {0167-2738},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {PreJuSER-9223},
year = {2010},
note = {Record converted from VDB: 12.11.2012},
abstract = {A decrease in the operating temperature of solid oxide fuel
cells below 700 degrees C results in a significant decrease
of the output power. In this temperature regime the ionic
resistance of the commonly used electrolyte
yttria-stabilized zirconia becomes dominant. Therefore, it
is necessary to reduce the thickness of the electrolyte
layer to minimize the resistance to ionic flow as long as no
alternative electrolyte materials with higher ionic
conductivity negligible electronic conductivity and
sufficient stability are available.In this paper electron
beam physical vapour deposition is discussed as a deposition
technology for thin electrolyte layers. An electrolyte
composite layer was developed with a lower specific
resistance in comparison to an electrolyte layer made by
vacuum slip-casting. The purpose of the composite
electrolyte was to fulfil both gas tightness and electronic
insulation.The performance of fully-assembled
anode-supported fuel cells with an electrolyte composite
manufactured by electron beam evaporation was 0.93 A/cm(2)
at 650 degrees C and 0.7 V. whereas the performance of cells
with an electrolyte manufactured by vacuum slip-casting with
a sintering step was 0.63 A/cm(2) at 650 degrees C and 0.7
V. The performance improvement was interpreted in terms of a
significantly different bulk ionic resistance of the
electrolyte layers. (C) 2010 Elsevier B.V. All rights
reserved.},
keywords = {J (WoSType)},
cin = {IEF-1 / JARA-ENERGY},
ddc = {530},
cid = {I:(DE-Juel1)VDB809 / $I:(DE-82)080011_20140620$},
pnm = {Rationelle Energieumwandlung / SOFC - Solid Oxide Fuel Cell
(SOFC-20140602)},
pid = {G:(DE-Juel1)FUEK402 / G:(DE-Juel1)SOFC-20140602},
shelfmark = {Chemistry, Physical / Physics, Condensed Matter},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000276781300012},
doi = {10.1016/j.ssi.2010.01.026},
url = {https://juser.fz-juelich.de/record/9223},
}