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@ARTICLE{Faassen:941216,
      author       = {Faassen, Fabian and Izarova, Natalya V. and van Leusen, Jan
                      and Kögerler, Paul},
      title        = {{B}ifunctionalized {P}olyoxotungstates: {D}ilacunary
                      {K}eggin {C}lusters {I}ncorporating {F}e {III} and
                      {O}rganoarsonate {C}onstituents},
      journal      = {Crystal growth $\&$ design},
      volume       = {23},
      number       = {1},
      issn         = {1528-7483},
      address      = {Washington, DC},
      publisher    = {ACS Publ.},
      reportid     = {FZJ-2023-00820},
      pages        = {434 - 441},
      year         = {2023},
      abstract     = {Polyanions
                      [{B-α-(OH)Fe2(PW10O37)}2{o-R–C6H4–AsO3)}2]12– (R =
                      NH2 (1) and NO2 (2)) represent the first polyoxotungstates
                      functionalized by both organoarsonates and FeIII. 1 and 2
                      comprise the rare dilacunary Keggin-type phosphotungstate
                      {B-α-PW10O37}9– isomer that coordinates FeIII ions to
                      form {B-α-FeIII2PW10} complexes linked into dimers via two
                      organoarsonate groups. The title polyanions have been
                      isolated as crystalline materials and fully characterized
                      via single-crystal and powder X-ray diffraction, elemental
                      analysis and IR and UV–vis spectroscopies, including
                      solution stability studies. In addition, their
                      electrochemical and magnetic properties have been
                      characterized.},
      cin          = {PGI-6},
      ddc          = {540},
      cid          = {I:(DE-Juel1)PGI-6-20110106},
      pnm          = {5213 - Quantum Nanoscience (POF4-521)},
      pid          = {G:(DE-HGF)POF4-5213},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000896920400001},
      doi          = {10.1021/acs.cgd.2c01100},
      url          = {https://juser.fz-juelich.de/record/941216},
}