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@ARTICLE{Hamill:943288,
author = {Hamill, Joseph and Zhour, Kazem and Diddens, Diddo and
Baghernejad, Masoud},
title = {{S}ignificant two-step potential-induced surface
reconstruction observed on {A}u(1 1 1) in aqueous sulfuric
acid},
journal = {Electrochemistry communications},
volume = {140},
issn = {1388-2481},
address = {Amsterdam [u.a.]},
publisher = {Elsevier Science},
reportid = {FZJ-2023-00898},
pages = {107332},
year = {2022},
abstract = {We report in this communication, through in situ STM images
correlated with time, and ab initio simulations of binding
energies, how potential-induced surface reconstruction is
formed on Au(1 1 1) single crystal in 0.1 M H2SO4. It was
found that while the electrode potential after lifting the
reconstructed surface is switched back to a more negative
value than the potential of zero charge, the formation
process of the reconstructed surface goes through two
consecutive routes. In the more kinetically favorable step,
and within a few minutes, the reconstructed surface follows
three different lattice directions with a high proportion of
semi zig-zag structures. However, by maintaining the
negative applied potential, the surface reconstruction
rearranges to a straighter reconstructed pattern in the
second step, which is more energetically favorable.},
cin = {IEK-12},
ddc = {540},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {1221 - Fundamentals and Materials (POF4-122) /
Elektrolytformulierungen für Lithiumbatterien der nächsten
Generation mit großer Energiedichte und hoher
Beständigkeit (13XP5129)},
pid = {G:(DE-HGF)POF4-1221 / G:(BMBF)13XP5129},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000891239800002},
doi = {10.1016/j.elecom.2022.107332},
url = {https://juser.fz-juelich.de/record/943288},
}