% IMPORTANT: The following is UTF-8 encoded.  This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.

@ARTICLE{Rosenbach:943460,
      author       = {Rosenbach, Carolin and Walther, Felix and Ruhl, Justine and
                      Hartmann, Matthias and Hendriks, Theodoor Anton and Ohno,
                      Saneyuki and Janek, Jürgen and Zeier, Wolfgang},
      title        = {{V}isualizing the {C}hemical {I}ncompatibility of {H}alide
                      and {S}ulfide‐{B}ased {E}lectrolytes in {S}olid‐{S}tate
                      {B}atteries},
      journal      = {Advanced energy materials},
      volume       = {13},
      number       = {6},
      issn         = {1614-6832},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2023-01031},
      pages        = {2203673},
      year         = {2023},
      abstract     = {Halide-based solid electrolytes are currently growing in
                      interest in solid-state batteries due to their high
                      electrochemical stability window compared to sulfide
                      electrolytes. However, often a bilayer separator of a
                      sulfide and a halide is used and it is unclear why such
                      setup is necessary, besides the instability of the halides
                      against lithium metal. It is shown that an electrolyte
                      bilayer improves the capacity retention as it suppresses
                      interfacial resistance growth monitored by impedance
                      spectroscopy. By using in-depth analytical characterization
                      of buried interphases by time-of-flight secondary ion mass
                      spectrometry and focused ion beam scanning electron
                      microscopy analyses, an indium-sulfide rich region is
                      detected at the halide and sulfide contact area, visualizing
                      the chemical incompatibility of these two electrolytes. The
                      results highlight the need to consider more than just the
                      electrochemical stability of electrolyte materials, showing
                      that chemical compatibility of all components may be
                      paramount when using halide-based solid electrolytes in
                      solid-state batteries.},
      cin          = {IEK-12},
      ddc          = {050},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000903650200001},
      doi          = {10.1002/aenm.202203673},
      url          = {https://juser.fz-juelich.de/record/943460},
}