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| 001 | 9900 | ||
| 005 | 20240619083323.0 | ||
| 024 | 7 | _ | |2 pmid |a pmid:20136092 |
| 024 | 7 | _ | |2 DOI |a 10.1021/jp910331a |
| 024 | 7 | _ | |2 WOS |a WOS:000274842600031 |
| 024 | 7 | _ | |2 Handle |a 2128/4670 |
| 024 | 7 | _ | |a altmetric:21804056 |2 altmetric |
| 037 | _ | _ | |a PreJuSER-9900 |
| 041 | _ | _ | |a eng |
| 082 | _ | _ | |a 530 |
| 084 | _ | _ | |2 WoS |a Chemistry, Physical |
| 100 | 1 | _ | |0 P:(DE-Juel1)VDB76355 |a Blanco, P. |b 0 |u FZJ |
| 245 | _ | _ | |a Study of the Soret Effect in Monosaccharide Solutions |
| 260 | _ | _ | |a Washington, DC |b Soc. |c 2010 |
| 300 | _ | _ | |a 2807 - 2813 |
| 336 | 7 | _ | |a Journal Article |0 PUB:(DE-HGF)16 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a article |2 DRIVER |
| 440 | _ | 0 | |0 3694 |a Journal of Physical Chemistry B |v 114 |x 1520-6106 |y 8 |
| 500 | _ | _ | |a We appreciate many fruitful discussions with Pavel Polyakov, Malte Kleemeier, and Gerd Meier. We thank Stefanie Jacob and Martina Bischop for their help with polarimeter measurements. We are also grateful for very helpful remarks by Stefan Immel. We thank the Department of Education, Universities and Investigation of Basque Government for the grant BFI08188.0. Financial support due to the Deutsche Forschungsgemeinschaft grant Wi 1684 is gratefully acknowledged. |
| 520 | _ | _ | |a We investigated the thermal diffusion behavior of aqueous solutions of monosaccharides with the infrared thermal diffusion forced Rayleigh scattering (IR-TDFRS) setup. As monosaccharides, we studied the three aldohexoses glucose, galactose, and mannose and the two ketohexoses sorbose and fructose. All sugars have the same molecular weight, but their structures differ as well as some physical properties such as viscosity, density, thermal expansion coefficient, and optical rotation. Additionally, we measured the viscosity and the optical rotation of the monosaccharide solutions in the investigated temperature and concentration range. While there is a clear correlation between the structure and the thermal diffusion behavior for alkanes, the situation is much more complicated for the monosaccharides. Nevertheless, as in the case of the alkanes, we find a correlation between the thermal diffusion coefficient with the ratio of the thermal expansion coefficient and the kinematic viscosity. We discuss the physical principles, which connect the thermal diffusion behavior with other thermophysical properties and the structure of the different sugars. |
| 536 | _ | _ | |0 G:(DE-Juel1)FUEK414 |2 G:(DE-HGF) |a Kondensierte Materie |c P54 |x 0 |
| 588 | _ | _ | |a Dataset connected to Web of Science, Pubmed |
| 650 | _ | 2 | |2 MeSH |a Diffusion |
| 650 | _ | 2 | |2 MeSH |a Molecular Structure |
| 650 | _ | 2 | |2 MeSH |a Monosaccharides: chemistry |
| 650 | _ | 2 | |2 MeSH |a Solutions: chemistry |
| 650 | _ | 2 | |2 MeSH |a Spectroscopy, Fourier Transform Infrared |
| 650 | _ | 2 | |2 MeSH |a Stereoisomerism |
| 650 | _ | 2 | |2 MeSH |a Temperature |
| 650 | _ | 2 | |2 MeSH |a Viscosity |
| 650 | _ | 7 | |0 0 |2 NLM Chemicals |a Monosaccharides |
| 650 | _ | 7 | |0 0 |2 NLM Chemicals |a Solutions |
| 650 | _ | 7 | |2 WoSType |a J |
| 700 | 1 | _ | |0 P:(DE-Juel1)131034 |a Wiegand, S. |b 1 |u FZJ |
| 773 | _ | _ | |0 PERI:(DE-600)2006039-7 |a 10.1021/jp910331a |g Vol. 114, p. 2807 - 2813 |p 2807 - 2813 |q 114<2807 - 2813 |t The @journal of physical chemistry |v 114 |x 1520-6106 |y 2010 |
| 856 | 7 | _ | |u http://dx.doi.org/10.1021/jp910331a |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/9900/files/4670.pdf |y OpenAccess |
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| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/9900/files/4670.jpg?subformat=icon-640 |x icon-640 |y OpenAccess |
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| 914 | 1 | _ | |y 2010 |
| 915 | _ | _ | |0 StatID:(DE-HGF)0010 |a JCR/ISI refereed |
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| 920 | 1 | _ | |0 I:(DE-Juel1)VDB787 |d 31.12.2010 |g IFF |k IFF-7 |l Weiche Materie |x 0 |
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