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@ARTICLE{LeCoeur:9932,
author = {Le Coeur, C. and Teixeira, J. and Busch, P. and Longeville,
S.},
title = {{C}ompression of random coils due to macromolecular
crowding: {S}caling effects},
journal = {Physical review / E},
volume = {81},
number = {6},
issn = {1539-3755},
address = {College Park, Md.},
publisher = {APS},
reportid = {PreJuSER-9932},
pages = {061914},
year = {2010},
note = {Record converted from VDB: 12.11.2012},
abstract = {The addition of a macromolecular crowding agent to a dilute
solution of polymer exerts a compressive force that tends to
reduce the size of the chain. We study here the effect of
changing the size ratio between the random coil and the
crowding agent. The compression occurs at lower crowding
agent concentration, Phi when polymer molecular weight
increases. The Flory exponent nu(Phi) decreases from
nu(0)similar or equal to 0.48 in water down to 0.3 with
macromolecular crowding. The effective polymer-polymer
interactions change from repulsive to strongly attractive
inducing aggregation of the chains. This effect changes
drastically for larger polymer sizes, being much more
pronounced at high molecular weights.},
keywords = {J (WoSType)},
cin = {IFF-4 / IFF-5 / Jülich Centre for Neutron Science JCNS
(JCNS) ; JCNS},
ddc = {530},
cid = {I:(DE-Juel1)VDB784 / I:(DE-Juel1)VDB785 /
I:(DE-Juel1)JCNS-20121112},
pnm = {BioSoft: Makromolekulare Systeme und biologische
Informationsverarbeitung / Großgeräte für die Forschung
mit Photonen, Neutronen und Ionen (PNI)},
pid = {G:(DE-Juel1)FUEK505 / G:(DE-Juel1)FUEK415},
experiment = {EXP:(DE-MLZ)KWS2-20140101},
shelfmark = {Physics, Fluids $\&$ Plasmas / Physics, Mathematical},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000278657500001},
doi = {10.1103/PhysRevE.81.061914},
url = {https://juser.fz-juelich.de/record/9932},
}