000999182 001__ 999182
000999182 005__ 20240712112839.0
000999182 0247_ $$2doi$$a10.1002/advs.202205012
000999182 0247_ $$2Handle$$a2128/33949
000999182 0247_ $$2pmid$$a36529956
000999182 0247_ $$2WOS$$aWOS:000899651100001
000999182 037__ $$aFZJ-2023-01216
000999182 082__ $$a624
000999182 1001_ $$0P:(DE-HGF)0$$aHou, An-Yuan$$b0
000999182 245__ $$aAll‐Solid‐State Garnet‐Based Lithium Batteries at Work–In Operando TEM Investigations of Delithiation/Lithiation Process and Capacity Degradation Mechanism
000999182 260__ $$aWeinheim$$bWiley-VCH$$c2023
000999182 3367_ $$2DRIVER$$aarticle
000999182 3367_ $$2DataCite$$aOutput Types/Journal article
000999182 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1677067653_20615
000999182 3367_ $$2BibTeX$$aARTICLE
000999182 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000999182 3367_ $$00$$2EndNote$$aJournal Article
000999182 520__ $$aLi7La3Zr2O12 (LLZO)-based all-solid-state Li batteries (SSLBs) are very attractive next-generation energy storage devices owing to their potential for achieving enhanced safety and improved energy density. However, the rigid nature of the ceramics challenges the SSLB fabrication and the afterward interfacial stability during electrochemical cycling. Here, a promising LLZO-based SSLB with a high areal capacity and stable cycle performance over 100 cycles is demonstrated. In operando transmission electron microscopy (TEM) is used for successfully demonstrating and investigating the delithiation/lithiation process and understanding the capacity degradation mechanism of the SSLB on an atomic scale. Other than the interfacial delamination between LLZO and LiCoO2 (LCO) owing to the stress evolvement during electrochemical cycling, oxygen deficiency of LCO not only causes microcrack formation in LCO but also partially decomposes LCO into metallic Co and is suggested to contribute to the capacity degradation based on the atomic-scale insights. When discharging the SSLB to a voltage of ≈1.2 versus Li/Li+, severe capacity fading from the irreversible decomposition of LCO into metallic Co and Li2O is observed under in operando TEM. These observations reveal the capacity degradation mechanisms of the LLZO-based SSLB, which provides important information for future LLZO-based SSLB developments.
000999182 536__ $$0G:(DE-HGF)POF4-1223$$a1223 - Batteries in Application (POF4-122)$$cPOF4-122$$fPOF IV$$x0
000999182 588__ $$aDataset connected to CrossRef, Journals: juser.fz-juelich.de
000999182 7001_ $$0P:(DE-HGF)0$$aHuang, Chih-Yang$$b1
000999182 7001_ $$0P:(DE-Juel1)156244$$aTsai, Chih-Long$$b2
000999182 7001_ $$0P:(DE-HGF)0$$aHuang, Chun-Wei$$b3
000999182 7001_ $$0P:(DE-Juel1)161348$$aSchierholz, Roland$$b4
000999182 7001_ $$0P:(DE-HGF)0$$aLo, Hung-Yang$$b5
000999182 7001_ $$0P:(DE-Juel1)161208$$aTempel, Hermann$$b6
000999182 7001_ $$0P:(DE-Juel1)157700$$aKungl, Hans$$b7
000999182 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b8$$eCorresponding author
000999182 7001_ $$0P:(DE-HGF)0$$aChang, Jeng-Kuei$$b9
000999182 7001_ $$0P:(DE-HGF)0$$aWu, Wen-Wei$$b10$$eCorresponding author
000999182 773__ $$0PERI:(DE-600)2808093-2$$a10.1002/advs.202205012$$gVol. 10, no. 5, p. 2205012 -$$n5$$p2205012 -$$tAdvanced science$$v10$$x2198-3844$$y2023
000999182 8564_ $$uhttps://juser.fz-juelich.de/record/999182/files/Advanced%20Science%20-%202022%20-%20Hou%20-%20All%E2%80%90Solid%E2%80%90State%20Garnet%E2%80%90Based%20Lithium%20Batteries%20at%20Work%20In%20Operando%20TEM%20Investigations%20of.pdf$$yOpenAccess
000999182 8564_ $$uhttps://juser.fz-juelich.de/record/999182/files/manuscript-revised.202302015.docx$$yOpenAccess
000999182 909CO $$ooai:juser.fz-juelich.de:999182$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000999182 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)156244$$aForschungszentrum Jülich$$b2$$kFZJ
000999182 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)161348$$aForschungszentrum Jülich$$b4$$kFZJ
000999182 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)161208$$aForschungszentrum Jülich$$b6$$kFZJ
000999182 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)157700$$aForschungszentrum Jülich$$b7$$kFZJ
000999182 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)156123$$aForschungszentrum Jülich$$b8$$kFZJ
000999182 9101_ $$0I:(DE-588b)36225-6$$6P:(DE-Juel1)156123$$aRWTH Aachen$$b8$$kRWTH
000999182 9131_ $$0G:(DE-HGF)POF4-122$$1G:(DE-HGF)POF4-120$$2G:(DE-HGF)POF4-100$$3G:(DE-HGF)POF4$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF4-1223$$aDE-HGF$$bForschungsbereich Energie$$lMaterialien und Technologien für die Energiewende (MTET)$$vElektrochemische Energiespeicherung$$x0
000999182 9141_ $$y2023
000999182 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2022-11-18
000999182 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000999182 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal$$d2018-07-06T12:17:41Z
000999182 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ$$d2018-07-06T12:17:41Z
000999182 915__ $$0StatID:(DE-HGF)0113$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2022-11-18
000999182 915__ $$0StatID:(DE-HGF)0700$$2StatID$$aFees$$d2022-11-18
000999182 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000999182 915__ $$0StatID:(DE-HGF)0561$$2StatID$$aArticle Processing Charges$$d2022-11-18
000999182 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bADV SCI : 2022$$d2023-08-29
000999182 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2023-08-29
000999182 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2023-08-29
000999182 915__ $$0StatID:(DE-HGF)0320$$2StatID$$aDBCoverage$$bPubMed Central$$d2023-08-29
000999182 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bDOAJ : Anonymous peer review$$d2018-07-06T12:17:41Z
000999182 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search$$d2023-08-29
000999182 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC$$d2023-08-29
000999182 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2023-08-29
000999182 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2023-08-29
000999182 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2023-08-29
000999182 915__ $$0StatID:(DE-HGF)9915$$2StatID$$aIF >= 15$$bADV SCI : 2022$$d2023-08-29
000999182 920__ $$lyes
000999182 9201_ $$0I:(DE-Juel1)IEK-9-20110218$$kIEK-9$$lGrundlagen der Elektrochemie$$x0
000999182 9801_ $$aFullTexts
000999182 980__ $$ajournal
000999182 980__ $$aVDB
000999182 980__ $$aUNRESTRICTED
000999182 980__ $$aI:(DE-Juel1)IEK-9-20110218
000999182 981__ $$aI:(DE-Juel1)IET-1-20110218