TY - JOUR
AU - Figueroa Miranda, Gabriela
AU - Liang, Yuanying
AU - Suranglikar, Mohit
AU - Stadler, Matthias
AU - Samane, Nagesh
AU - Tintelott, Marcel
AU - Lo, Young
AU - Tanner, Julian A.
AU - Vu, Duy Tam
AU - Knoch, Joachim
AU - Ingebrandt, Sven
AU - Offenhäusser, Andreas
AU - Pachauri, Vivek
AU - Mayer, Dirk
TI - Delineating charge and capacitance transduction in system-integrated graphene-based BioFETs used as aptasensors for malaria detection
JO - Biosensors and bioelectronics
VL - 208
SN - 0956-5663
CY - Amsterdam [u.a.]
PB - Elsevier Science
M1 - FZJ-2023-01333
SP - 114219
PY - 2022
AB - Despite significant eradication efforts, malaria remains a persistent infectious disease with high mortality due to the lack of efficient point-of-care (PoC) screening solutions required to manage low-density asymptomatic parasitemia. In response, we demonstrate a quantitative electrical biosensor based on system-integrated two-dimensional field-effect transistors (2DBioFETs) of reduced graphene oxide (rGO) as transducer for high sensitivity screening of the main malaria biomarker, Plasmodium falciparum lactate dehydrogenase (PfLDH). The 2DBioFETs were biofunctionalized with pyrene-modified 2008s aptamers as specific PfLDH receptors. While we systematically optimize biosensor interface for optimal performance, aptamer-protein transduction at 2DBioFETs is elucidated based on delineation of charge and capacitance in an updated analytical model for two-dimensional rGO/biofunctional layer/electrolyte (2DiBLE) interfaces. Our 2DBioFET-aptasensors display a limit-of-detection down to 0.78 fM (0.11 pg/mL), dynamic ranges over 9 orders of magnitude (subfemto to submicromolar), high sensitivity, and selectivity in human serum validating their diagnostic potential as rapid PoC tests for malarial management.
LB - PUB:(DE-HGF)16
C6 - 35367704
UR - <Go to ISI:>//WOS:000792492900006
DO - DOI:10.1016/j.bios.2022.114219
UR - https://juser.fz-juelich.de/record/1005145
ER -