guest ::
| Home > Publications database > A conformally bonded molecular interface retarded iodine migration for durable perovskite solar cells > print |
| Home > Publications database > A conformally bonded molecular interface retarded iodine migration for durable perovskite solar cells > print |
| 001 | 1006591 | ||
| 005 | 20240712113008.0 | ||
| 024 | 7 | _ | |a 10.1039/D2EE03565K |2 doi |
| 024 | 7 | _ | |a 1754-5692 |2 ISSN |
| 024 | 7 | _ | |a 1754-5706 |2 ISSN |
| 024 | 7 | _ | |a 2128/34319 |2 Handle |
| 024 | 7 | _ | |a WOS:000941368100001 |2 WOS |
| 037 | _ | _ | |a FZJ-2023-01732 |
| 082 | _ | _ | |a 690 |
| 100 | 1 | _ | |a Yuan, Ligang |0 0000-0001-6505-3232 |b 0 |
| 245 | _ | _ | |a A conformally bonded molecular interface retarded iodine migration for durable perovskite solar cells |
| 260 | _ | _ | |a Cambridge |c 2023 |b RSC Publ. |
| 336 | 7 | _ | |a article |2 DRIVER |
| 336 | 7 | _ | |a Output Types/Journal article |2 DataCite |
| 336 | 7 | _ | |a Journal Article |b journal |m journal |0 PUB:(DE-HGF)16 |s 1681973953_22905 |2 PUB:(DE-HGF) |
| 336 | 7 | _ | |a ARTICLE |2 BibTeX |
| 336 | 7 | _ | |a JOURNAL_ARTICLE |2 ORCID |
| 336 | 7 | _ | |a Journal Article |0 0 |2 EndNote |
| 520 | _ | _ | |a State-of-the-art n–i–p perovskite solar cells (PSCs) suffer from stability issues due to ionic interdiffusion. Herein, by enlarging the indacenodithiophene π-bridge donor (D′) to combine with the methoxy triphenylamine donor (D) and benzothiadiazole acceptor (A), three linear molecules termed L1, L2 and L3 with a D–A–D′–A–D structure are developed as dopant-free hole transport materials (HTMs). The π-bridge extension with active sites for coordination leverages the intramolecular dipole effect and intermolecular packing effect, resulting in a conformally bonded ultrathin interface with compact and uniform coverage (∼60 nm) to retard iodine migration and protect the buried perovskite. The unencapsulated L3-PSC (ITO/SnO2/perovskite/L3/MoO3/Au) achieved an impressive PCE of 22.61% (certified 21.79%, 0.0525 cm2). Ultrafast laser spectroscopy reveals that L-series molecules have a sequential reduction of photoexcited energy disorder to illustrate the structure–performance–stability relationship. L3-PSC maintains over 85% of the initial efficiency after 500 h at 85 °C maximum power point tracking (MPP) and enables the possibility of using small molecules to stabilize n–i–p PSCs. |
| 536 | _ | _ | |a 1213 - Cell Design and Development (POF4-121) |0 G:(DE-HGF)POF4-1213 |c POF4-121 |f POF IV |x 0 |
| 536 | _ | _ | |a 1212 - Materials and Interfaces (POF4-121) |0 G:(DE-HGF)POF4-1212 |c POF4-121 |f POF IV |x 1 |
| 588 | _ | _ | |a Dataset connected to CrossRef, Journals: juser.fz-juelich.de |
| 700 | 1 | _ | |a Zhu, Weiya |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Zhang, Yiheng |0 P:(DE-HGF)0 |b 2 |
| 700 | 1 | _ | |a Li, Yuan |0 0000-0002-7931-9879 |b 3 |e Corresponding author |
| 700 | 1 | _ | |a Chan, Christopher C. S. |0 P:(DE-HGF)0 |b 4 |
| 700 | 1 | _ | |a Qin, Minchao |0 P:(DE-HGF)0 |b 5 |
| 700 | 1 | _ | |a Qiu, Jianhang |0 0000-0002-7029-1523 |b 6 |
| 700 | 1 | _ | |a Zhang, Kaicheng |0 P:(DE-HGF)0 |b 7 |
| 700 | 1 | _ | |a Huang, Jiaxing |0 P:(DE-HGF)0 |b 8 |
| 700 | 1 | _ | |a Wang, Jiarong |0 P:(DE-HGF)0 |b 9 |
| 700 | 1 | _ | |a Luo, Huiming |0 P:(DE-HGF)0 |b 10 |
| 700 | 1 | _ | |a Zhang, Zheng |0 P:(DE-HGF)0 |b 11 |
| 700 | 1 | _ | |a Chen, Ruipeng |0 P:(DE-HGF)0 |b 12 |
| 700 | 1 | _ | |a Liang, Weixuan |0 P:(DE-HGF)0 |b 13 |
| 700 | 1 | _ | |a Wei, Qi |0 P:(DE-HGF)0 |b 14 |
| 700 | 1 | _ | |a Wong, Kam Sing |0 P:(DE-HGF)0 |b 15 |
| 700 | 1 | _ | |a Lu, Xinhui |0 P:(DE-HGF)0 |b 16 |
| 700 | 1 | _ | |a Li, Ning |0 P:(DE-Juel1)180778 |b 17 |e Corresponding author |
| 700 | 1 | _ | |a Brabec, Christoph |0 P:(DE-Juel1)176427 |b 18 |
| 700 | 1 | _ | |a Ding, Liming |0 0000-0001-6437-9150 |b 19 |
| 700 | 1 | _ | |a Yan, Keyou |0 0000-0003-4380-7325 |b 20 |e Corresponding author |
| 773 | _ | _ | |a 10.1039/D2EE03565K |g p. 10.1039.D2EE03565K |0 PERI:(DE-600)2439879-2 |n 3 |p 1597-1609 |t Energy & environmental science |v 16 |y 2023 |x 1754-5692 |
| 856 | 4 | _ | |u https://juser.fz-juelich.de/record/1006591/files/d2ee03565k-1.pdf |y Restricted |
| 856 | 4 | _ | |y Published on 2023-02-01. Available in OpenAccess from 2024-02-01. |u https://juser.fz-juelich.de/record/1006591/files/A%20conformally%20bonded%20molecular%20interface%20retarded%20iodine%20migration%20for%20durable%20perovskite%20solar%20cells.pdf |
| 909 | C | O | |o oai:juser.fz-juelich.de:1006591 |p openaire |p open_access |p VDB |p driver |p dnbdelivery |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 17 |6 P:(DE-Juel1)180778 |
| 910 | 1 | _ | |a Forschungszentrum Jülich |0 I:(DE-588b)5008462-8 |k FZJ |b 18 |6 P:(DE-Juel1)176427 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Energie |l Materialien und Technologien für die Energiewende (MTET) |1 G:(DE-HGF)POF4-120 |0 G:(DE-HGF)POF4-121 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-100 |4 G:(DE-HGF)POF |v Photovoltaik und Windenergie |9 G:(DE-HGF)POF4-1213 |x 0 |
| 913 | 1 | _ | |a DE-HGF |b Forschungsbereich Energie |l Materialien und Technologien für die Energiewende (MTET) |1 G:(DE-HGF)POF4-120 |0 G:(DE-HGF)POF4-121 |3 G:(DE-HGF)POF4 |2 G:(DE-HGF)POF4-100 |4 G:(DE-HGF)POF |v Photovoltaik und Windenergie |9 G:(DE-HGF)POF4-1212 |x 1 |
| 914 | 1 | _ | |y 2023 |
| 915 | _ | _ | |a Embargoed OpenAccess |0 StatID:(DE-HGF)0530 |2 StatID |
| 915 | _ | _ | |a National-Konsortium |0 StatID:(DE-HGF)0430 |2 StatID |d 2023-10-25 |w ger |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0300 |2 StatID |b Medline |d 2023-10-25 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0199 |2 StatID |b Clarivate Analytics Master Journal List |d 2023-10-25 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0150 |2 StatID |b Web of Science Core Collection |d 2023-10-25 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1060 |2 StatID |b Current Contents - Agriculture, Biology and Environmental Sciences |d 2023-10-25 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1160 |2 StatID |b Current Contents - Engineering, Computing and Technology |d 2023-10-25 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)1150 |2 StatID |b Current Contents - Physical, Chemical and Earth Sciences |d 2023-10-25 |
| 915 | _ | _ | |a JCR |0 StatID:(DE-HGF)0100 |2 StatID |b ENERG ENVIRON SCI : 2022 |d 2023-10-25 |
| 915 | _ | _ | |a DBCoverage |0 StatID:(DE-HGF)0200 |2 StatID |b SCOPUS |d 2023-10-25 |
| 915 | _ | _ | |a IF >= 30 |0 StatID:(DE-HGF)9930 |2 StatID |b ENERG ENVIRON SCI : 2022 |d 2023-10-25 |
| 920 | _ | _ | |l yes |
| 920 | 1 | _ | |0 I:(DE-Juel1)IEK-11-20140314 |k IEK-11 |l Helmholtz-Institut Erlangen-Nürnberg Erneuerbare Energien |x 0 |
| 980 | 1 | _ | |a FullTexts |
| 980 | _ | _ | |a journal |
| 980 | _ | _ | |a VDB |
| 980 | _ | _ | |a UNRESTRICTED |
| 980 | _ | _ | |a I:(DE-Juel1)IEK-11-20140314 |
| 981 | _ | _ | |a I:(DE-Juel1)IET-2-20140314 |
| Library | Collection | CLSMajor | CLSMinor | Language | Author |
|---|