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@ARTICLE{Chiou:1006634,
      author       = {Chiou, Min-Huei and Verweyen, Elisabeth and Diddens, Diddo
                      and Wichmann, Lennart and Schmidt, Christina and Neuhaus,
                      Kerstin and Choudhary, Aditya and Bedrov, Dmitry and Winter,
                      Martin and Brunklaus, Gunther},
      title        = {{S}election of {P}olymer {S}egment {S}pecies {M}atters for
                      {E}lectrolyte {P}roperties and {P}erformance in {L}ithium
                      {M}etal {B}atteries},
      journal      = {ACS applied energy materials},
      volume       = {6},
      number       = {8},
      issn         = {2574-0962},
      address      = {Washington, DC},
      publisher    = {ACS Publications},
      reportid     = {FZJ-2023-01767},
      pages        = {4422–4436},
      year         = {2023},
      abstract     = {Control of homogeneous lithium deposition governs prospects
                      of advanced cell development and practical applications of
                      high-energy-density lithium metal batteries. Polymer
                      electrolytes are thus explored and employed to mitigate the
                      growth of high-surface-area lithium species while enhancing
                      the reversibility of the lithium reservoir upon cell
                      cycling. Herein, an in-depth understanding of the
                      distribution of membrane properties and lithium deposition
                      behavior affected by the selection of polymer segment
                      species is derived. It is demonstrated that severely
                      localized lithium deposits featuring needle-like
                      morphologies may be readily observed when electrostatic
                      fields (or partial charges) and the amount of Li+
                      coordinators of the primary and secondary polymer segment
                      species appear rather dissimilar, leading to a sudden cell
                      failure at early stages of cell operation. In comparison,
                      employment of optimized copolymer electrolytes enables
                      superior cell performance at 1C even with thicker cathodes
                      (6.3 mg cm–2). Additionally, the improvement of
                      cell-cycling stability due to enhancement of similarity of
                      dipole moments and partial charge distributions among
                      copolymer segments are also demonstrated for different
                      polymer systems, contributing to avoidance of undesired
                      lithium protrusions, also reflecting a viable concept for
                      the design of future copolymer electrolytes.},
      cin          = {IEK-12},
      ddc          = {540},
      cid          = {I:(DE-Juel1)IEK-12-20141217},
      pnm          = {1221 - Fundamentals and Materials (POF4-122) / 1222 -
                      Components and Cells (POF4-122) / 1223 - Batteries in
                      Application (POF4-122)},
      pid          = {G:(DE-HGF)POF4-1221 / G:(DE-HGF)POF4-1222 /
                      G:(DE-HGF)POF4-1223},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000973157300001},
      doi          = {10.1021/acsaem.3c00571},
      url          = {https://juser.fz-juelich.de/record/1006634},
}